Paraphrasing .ewriting Tool Car notePirate ShipBLACKBOARD[Review Topics][References]Specify the types of strain that destabilize the conformer shown below. Hint: All bonds not explicitly shown are in thestaggered conformation.1. Torsional strain2. Angle (ring) strain3. Steric (van der Waals) strainH.HH.H3CCH3CH3PreviousNextSave and ExitétvO 14MacBook AirDIDD80888F12FBF9F10F11F3F4F5F7$&46{TYU11FH.K* CO

[Review Topics) [References) Specify the types of strain that destabilize the conformer shown below. Hint: All bonds not explicitly shown are in th staggered conformation. 1. Torsional strain 2. Angle (ring) strain 3. Steric (van der Waals) strain H. H3C. CH3 CH3

[Review Topics) [References) Specify the types of strain that destabilize the conformer shown below. Hint: All bonds not explicitly shown are in th staggered conformation. 1. Torsional strain 2. Angle (ring) strain 3. Steric (van der Waals) strain H. H3C. CH3 CH3

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter6: Alkanes & Alkenes

Section: Chapter Questions

Problem 4E: Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This...

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Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

Paraphrasing .ewriting Tool Car note
Pirate Ship
BLACKBOARD
[Review Topics]
[References]
Specify the types of strain that destabilize the conformer shown below. Hint: All bonds not explicitly shown are in the
staggered conformation.
1. Torsional strain
2. Angle (ring) strain
3. Steric (van der Waals) strain
H.
H
H.
H3C
CH3
CH3
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Next
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étv
O 14
MacBook Air
DI
DD
80
888
F12
FB
F9
F10
F11
F3
F4
F5
F7
$
&
4
6
{
T
Y
U
11
F
H.
K
* CO

Expert Solution

Step 1

Torsional strain is generated when two groups are placed at 1 and 3 positions with respect to eachother .

Thus this strain is more prominent for equitorial bonds

In small rings like cyclopropane , cyclobutane etc

Bond angle predicted from ring size is less than that expected from hybridization state. Thus angle strain is generated.

Steric strain is generated if two large groups are in close proximity i.e. within an angle of 0- 60°

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