Rank the following in order of increasing rate of solvolysis in methanol. Give a BRIEF explanation that includes drawings of the intermediate carbocations for each structure: :ĊI: :CI: A B CI: C V slowest fastest
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- (b) acid, HNO3 to produce compound L. The reaction of compound L with bromine, Br2 in the presence of iron tribromide, FeBr3 produced compound M. Benzene also undergoes Fridel-crafts alkylation reaction with chloroethane, CH;CH2CI using catalyst N to produce compound P. Benzene, CeHe undergoes substitution reaction with concentrated nitric Benzena, CsHe menjalani tindak balas penukargantian dengan asid nitrik, HNO, pekat untuk menghasilkan sebatian L. Tindak balas sebatian L dengan bromin, Brz dengan kehadiran ferum tribromida, FeBrs menghasilkan sebatian M. Benzena juga menjalani tindak balas alkilasi Fridel-crafts dengan kloroetana, CH3CH2CI dengan menggunakan pemangkin N untuk menghasilkan sebatian P. (i) Draw the structural formula of L, M and P. Lukiskan formula struktur bagi sebatian L, M dan P. (ii) State catalyst N. Nyatakan pemangkin N. (iii) Show the formation of electrophile that will be reacted with benzene for the formation of compound P.The main organic product for the reaction under heating is:Bromine reacts with alkenes in methanol according to the equation: - When this reaction was carried out with 4-tert-butylcyclohexene, only one isomer was formed with the molecular formula C12H23BrO (80% yield). Which of the following is the structure more reasonable for this compound?. Explain your reasoning through acorresponding mechanism.
- provide the major profucts ( wrote "no reaxtion "if you think so) for the following reactions with correct stereochemistry. Please explain step by step with explanationdivls depends oin the moisture content of the reaction mixture. Propose a detailed mechanism for ench of the following steps to account for the observed The outeome of oxidation of alkenes with 1odine and silver acetate to afford stereochemistry of the product HO () 2, 2 RCO2Ag (i1) NaOH (aq) HO HO () 2, RCO2Ag, H20 (11) NaOH (aq) HOArrange the following compounds according to their rate of solvolysis with suitable explanation.
- Provide the structure of the major organic product of the following reaction and? explain the stereochemistry which results in this product. 2-Pentanol reacting with 1.) PBr3, pyridine 2.) NaCNCompounds with more than one hydroxyl group can react with thionyl chloride of differently from simple alcohols. In reaction with thionyl chloride, butane-1,2-diol gave a single organic product with 85% yield, according to the following balanced equation: Suggest through a mechanism, a reasonable structure for this productGive the major organic product(s) of the following. Include stereochemistry when applicable. 1) Nal Br a) 2) NACN, acetone I) NAOC(CH,),, heat b) Br 2) BH; THF; 3) H,O,. NaOH(aq) 1) HCI 2) KOCICH,), heat 1) NAOH, heat Br 2) МСРВА 1) KOC(CH,), heat Br e) 2) H,0"
- Devise efficient laboratory syntheses of ethers and epoxides, including the following:(a) The Williamson ether synthesis(b) Alkoxymercuration-demercuration(c) Peroxyacid epoxidation(d) Base-promoted cyclization of halohydrins(e) Formation of silyl ethersStereochemistry and pKa Ivermectin is an antibacterial and antiparascitic natural product that is produced by fermentation cultures of the bacteria Streptomyces avermectilis. It is an inexpensive and well-tolerated treatment for river blindness in humans caused by the parasitic nematode Onchocerce volvulus. It is also an excellent horse dewormer. There is no scientific evidence that is has any effect on SARS-COV2. Please examine the chemical structure carefully and answer the questions that follow. In the circles please assign (E) or (Z) configuration to the double bonds indicated with an arrow. In the boxes please assign the absolute configuration i.e. (R) or (S) to the stereogenic centers indicated with an arrow. In the triangle please provide an approximate value for the pKa of the protons indicated with an arrow. Meo HO O MeO НО HOWhich of the following best describes a key step in the mechanism for the reaction below? HO, ... -CH3 -CH3 + en dihydroxylation H3C- H3C- OH (A) free-radical substitution at the carbonyl carbon B elimination reaction by abstraction of a beta-hydrogen nucleophilic attack by an alkene to form a cyclic (epoxide) intermediate electrophilic addition reaction to form a carbocation intermediate