Q1 (Conformation & Structure) a) When the molecule below is placed in the most stable chair conformation, how many halogens are in the axial position? Note that tBu = tertiary butyl 0 B 1 E 2 3 4 5 Br tBu ...O CI F F CI ...

Q1 (Conformation & Structure) a) When the molecule below is placed in the most stable chair conformation, how many halogens are in the axial position? Note that tBu = tertiary butyl 0 B 1 E 2 3 4 5 Br tBu ...O CI F F CI ...

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter7: Cycloalkanes

Section: Chapter Questions

Problem 12CTQ: Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth...

See similar textbooks

Related questions

Q: 7. Un catalizador aumenta la velocidad de una reacción porque

A: catalyst speed of reactions by lowering the activation energy catalyst increase reactions raids in…

Q: Which of the following is/are more soluble in this solvent than in water? BaCl2

A: Water is a polar solvent and it can dissolve an ionic or polar covalent compound.

Q: Give the starting materials. NaNH2

A: The terminal alkyne contains acidic hydrogen. The hydrogen atom attached to the sp hybridized carbon…

Q: If a column was run on the sample shown in lane 3, what would be the first compound to elute off of…

A: We have find out the answer.

Q: The Lewis Structure of QO32-, shows that the compound forms: (Q is the element symbol for Quinium…

A: Lewis Structure is simplified representation of the valence shell electrons in a molecule. It is…

Q: How many secondary carbons atoms does the compound below have, if any?

A: The classification of carbon atoms is done on the basis of the number of carbon atoms attached to…

Q: Is this reaction an oxidation or a reduction? neither oxidation reduction OH this response. i

Q: Why are stable orbitals for an electron classically forbidden?

A: Orbitals with less energy are more stable. A full-filled orbital is more stable than an orbital that…

Q: 1. Write the balanced equation for the production of brown nitrogen dioxide (NO₂) gas from nitrogen…

A: The overall reaction for the formation of NO2 from nitrogen and oxygen cam be obtained by…

Q: The radioactive nuclide has a half-life of 17.5 hours. What mass of the nuclide remains from a…

Q: What weight of sample should be taken for analysis sos that the volume of 0.1074N NaOH used for…

A: Using the concept of acid-base reaction and reaction stoichiometry, mass of sample can be…

Q: What is the potential of a non-standard condition galvanic cell formed by an Al electrode in a 1M…

A: A galvanic cell is a type of electrochemical cell that uses a spontaneous redox reaction to generate…

Q: The reaction 2H₂O₂ 2H₂O + O₂ has the following pathway: H₂O₂ + H₂O +10 H₂O₂ +10 H₂O+O₂ +1 The…

A: Given : reaction

Q: n-Butylamine is made by reaction of O cyanide, followed by reduction with lithium aluminum hydride.…

Q: O O The solubility of BaCO3(s) in water at a certain temperature is 3.9 x 10-5 mol/L. Calculate the…

Q: What is the expected outcome (A-D) for this synthesis? OA ОВ Ос 1) MeMgBr 2) H30+ А. B. С. D. OH OMe…

Q: What is the hybridization of the nitrogen atom below? O sp3 O sp² O sp OP IZ

A: Answer:- This question is answered by using the simple concept of determination of hybridization of…

Q: calculate the intracellular concentration of K+ that would be in equilibrium with an external…

A: Given, External concentration = 1.28mM Membrane potential =Ek= -213 mV = -0.213 V Temperature =…

Q: Perform the following conversion of pressure units: 155 torr = O O 1.53 10.50 0.204 4.90 atm

A: Explanation: Torr = 760 atm 760 torr are equivalent to 1 atm. The unit for measuring pressure in…

Q: Which statement describes the conformations below? H₂CCI H CI H 'H HH The staggered conformation on…

A: Staggered conformation - The atoms are arranged in a molecule in such a way that the dihedral angle…

Q: Combine the half-reactions IO3 - ---------- I2 and MnO4- ------- Mn2+ to form a proper redox…

A: Half reactions can be combined to give the final redox reaction in such a way that total electronic…

Q: What mass of Mg is formed by passing a current of 129 A through molten MgCl2, for 9.50 days?

A: Reaction- Mg2+ + 2 e- ------------> Mg(s)

Q: Which of the following would represent the greatest pressure? 0.662 atm 265 mmHg 12.2 psi 65465 Pa…

A: Given, the pressure values: 0.662 atm 265 mmHg 12.2 psi 65465 Pa 21.8 in We have to find the value…

Q: What is the maximum mass of gallium bromide that can be dorm when reacting 41 g of gallium with 38 g…

Q: 1 A M Question 16 CH3 Assign the stereochemistry as R or S.

A: RS nomenclature: The RS nomenclature is an important nomenclature system for denoting the…

Q: When acetylene gas, C₂H₂, burns, how many liters of O₂ at STP are used for every 7.78 mol of…

A: Given, Moles of the Acetylene = 7.78 mol STP means Standard Temperature and Pressure. Th formulae…

Q: A solution that has not reached the limit of solute that will dissolve in it is said to be…

A: There are two types of solution on basis of the addition of more amount of solute- 1- saturated…

Q: If you measured the rotation of a compound at 4.050 in a cell that is 0.35 dm in length. And your…

A: The information given is The optical rotation of a compound = 4.05 ° Length of the cell = 0.35 dm…

Q: What reagents (i.e., H2O H2SO4 and in that order) are appropriate to carry out the conversion shown?…

A: Identify the best reagents for the above organic conversion.

Q: HO MeoH

A: If the alkene reacts with the alcohols like methanol in presence of acid produced alkoxy substituted…

Q: In order to form a tertiary alcohol, excess CH MgBr could react with which one(s) of these…

A: Organic reactions are those in which organic reactant react to form organic products. In the given…

Q: Balance the Redox Reaction given below: MnSO4 + NaBiO3 + H2SO4 ⟶ NaMnO4 + Bi2(SO4)3 + H2O + Na2SO4

Q: How do I find out how many protons an atom has?

A: We have to find out the number of protons in an atom.

Q: How many acetyl CoA, ATP, and NADPH are required for the synthesis of a C10 fatty acid? O 5 acetyl…

A: 23A) 5 acetyl CoA, 4 ATP, and 8 NADPH Reason :- during fatty acid synthesis each round of…

Q: N-ethyl-6-methyl-5-propyl-3-nonanamine 4-butyl-1,2-dimethylcyclohexanol

Q: Use standard reduction potentials to calculate the equilibrium constant for the reaction: 2Fe³+ (aq)…

Q: Predict the major product for the following reaction. Enter the InChl code for the major product. H…

Q: Use standard reduction potentials to find the equilibrium constant for the following reaction at…

Q: Given the following unbalanced redox reaction: Fe(OH)3 + OCl- → FeO42- + Cl- What is the oxidation…

Q: What is the major organic product obtained in the following reaction? NH NH3 NaBH3CN II NH₂ III HỌ…

A: In a reductive amination reaction, a carbonyl compound reacts with ammonia or amine to form an imine…

Q: Which of the following molecules are chiral?

A: The molecule is said to be chiral if - 1- there should be atleast one chiral center 2- there should…

Q: Give a clear handwritten answer with explanation

Q: How much energy is needed to convert 59.5 grams of ice at 0.00 °C to water at 60.9 °CT specific heat…

A: Here, we have to find the amount of heat that is needed to convert 59.5 g of ice at 0.00 oC to water…

Q: The 121 howitzer refers to the bore size of the weapon in mm. Thus, the "121" has a 121 mm bore…

A: Given: Bore size = 121 mm and bore size in caliber = bore size in inches *100 since 1 in = 2.54 cm…

Q: 19. List the quantum numbers of all states in the 4d subshell of hydrogen in the (n, l, me, ms)…

A: Quantum numbers- These are the set of quantum numbers that are used to indicate the state, position,…

Q: Consider the following fatty acids: 0 CH₂-(CH₂)2-C-OH Myristic Acid

A: Solution: We know fatty acids generally contain a high number of carbons usually greater than 4.…

Q: . The standard Gibbs energy of the reaction N2 (g) + 3 H2 (g) → 2 when Q NH3 (g) is -32.9 kJ/mol at…

Q: Which of the following is the Bremsted-Lowry definition of an acid? A substance that produces H*…

A: Bronsted Lowry base : Bronsted Lowry base is that substance that accepts protons(H+ ions) in…

Q: 5) A 250.0 mL sample of 0.350 M acetic acid (Ka = 1.78 x 10-5) reacted with 2.250 L of gaseous NH3…

A: a) pH = pKa + log([A-]/[HA]) where [A-] is the concentration of the conjugate base, [HA] is the…

Q: 4 Listen You mix 100.0 mL of a 0.100 M NaOH solution and 150.0 mL of a 0.100 M HCI solution.…

Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

please do with clear handwritting and explanation

Q1
(Conformation & Structure)
a) When the molecule below is placed in the most stable chair conformation, how many halogens are in the axial position? Note
that tBu = tertiary butyl
0
B 1
E
2
3
4
5
Br
tBu
...O
CI
F
F
CI
...

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.
What chair structure corresponds to the highest energy conformation of trans-1,4-dichlorocyclohexane (shown on left)? CI CI CI CI CI CI CI .CI CI A C D CI B O O O O
By considering viewed through the C-2-C-3 bond, which below conformations of 2,3- dibromobutane show the most stable and the least stable conformation? Clearly explain the reason, why? S CH3 H H Br. H3C, Br H3C Br Br Br H. Br CH3 ČH3 H I II III Br Br H3C, Br H3C H. H3C" H. Br ČH3 IV V
Perspective drawings of Chair and Boat Conformers fo Cyclohexane (C6H12). Note it is impossible to place all the carbons in the same plane without straining the bonds. Take two opposite carbons and pull both of them up to make one conformation adn then pull one of them down to make the other conformation. Can you inercovert one conformer int othe other without breaking any bonds? Explain why these represent conformers and not isomers.
By considering viewed through the C-2-C-3 bond, which below conformations of 2,3- dibromobutane show the most stable and the least stable conformation? Clearly explain the reason, why? CH3 H Br. H3C, Br H3C H3Č Br Br Br H. ČH3 Br CH3 H I II III Br Br Br H3C. H3C ČH3 H. H3C H. Br IV V
Order the conformations of butane from lowest energy to highest energy (1 being the lowest energy). CH₂ H. H A B C D H A CH₂ H H₂ H CH3 CH₂ B H 'H H₂C CH₂ H H 4 1 3 2 -H 'H H H CH₂ H D -CH₂ H
Compare the following conformers of 1-fluoropropan-1-ol. Match each conformer to their corresponding relative energy. Recall, the more stable the conformer the lower the energy. OH CH3 'F 2. HOH 2nd Highest Energy H 2nd Lowest Energy H3C 3. H. ОН Lowest Energy H 'F Highest Energy ČH3 4. H3C, OH 'F 1. >
Draw the two chair cyclohexane conformations for the compound shown below. How many substituents are equatorial in the less stable conformation? CI" O معه O O 2 JI... CI ""CI
For the following structural formula, pick the structure that accurately represents its MOST STABLE conformation. CH3 H₂Cl... Br Br Br H₂C O D. O B. O C. O A. CH3 A CH3 B CH3 ... Br 주 Br H3C C CH3 H3C CH3 D
6) Draw the energetically favored (more stable) chair conformer of the following cyclohexane. H3C OH 110
Consider pentane, C5H12. Looking through the internal C3-C4single bond, draw thesix Newman projections (where the angle between two bonds as you look through the C3and C4bond is either 0°or 60°of the different conformations. Label the conformers/rotamers using I, II, etc. a.Which conformer is the most stable? the least stable? b.Which rotamer is the anticonformer? the gaucheconformer? c.Draw the anticonformer in saw horse projection.
1E.) Which of the following two conformers is lower in energy? Both conformers are of equal enery O A Conformer A is lower in energy. B Conformer B is lower in energy. It cannot be determined