ProVide the major prochuct for each following reactuns H more Than one 5 formed, Circk the major Produ ct -> 2. NBS, hy 1- Bra, FeBr3 2. H2504 -503H J.Bra, FeBr3 2. Mgco) 3. CH2O 4. H307 workup
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- What is the missing reactant in step 2 of the following reaction sequence? H* / H20 d-oC,Hs ? (1) LDA (-78°C) THF II CH,0-C-oC,H; CH3- -OCH5 II IV CH;-OC,H; H Select one: A. I В. IV O C. I| D. IIDtermine the Products from the rxn Me. LDA A CH;I B + Lil -70 °C The Products A and B are Ме Me CH3 A= B= А. Me Me Me A= B= В. OCH3 Me. Me. A= B= С. Me Me. Me A= B= D.What is the intermediate before the final product of the following reactions? ii NaOH H* heat O a. Na Ob. OH OH Od. Na* он e. Of.
- product? Uod c). Br Pd cat CO2CH3 1. LDA 2. H2C=0 3. Н.ОCH3 CH3 H3C N. H Tetracaine Tetracaine can be synthesized from benzene. The synthesis involves the following steps: 1. Benzene + CH3CI, AICI3 to form product A; 2. A + HNO3, H2SO4 to form product B; 3. B + KMNO4, H2O to form product C; 4. C + SOCI, to form product D; 5. D + HOCH2CH2N(CH3)2 to form product E; 6. E + H2, Pt to form product F; 7. F + CH3CH2CH2CHO to form product G; 8. G + NABH3CN to form Tetracaine. Draw the structures of product A and product G. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Show the order of synthesis by drawing a reaction arrow between A and G, pointing toward the later-synthesized product.GUSUIN CI- H. eviaoxe (MCPBA) elugelom ert notageta brs ainepse pnileil elom ert not eg CH3OH catalytic H2SO4
- Paused Complete the following reactions. 1. +H₂O NaBH mild oxidation Complete the following reactions. 1. Base cat. H3CH2C CH₂CH + H3CH2C- C -CH2CH3 2. OCH3 H3C-C -CH2CH3 + H₂O OCH3 3. 4. CH3 NaBH4 H3CH2C C CH2CH3 + CH3CH2OH 5. mild oxidation1) quv LDA Endicate the product in bex and indicate whech is the thermady namil or Kinetic produet CampandE 11 qur LDA D 2) H3C. CH3CH20H Kinetic or thermadynumc 31 HyoT Protonutish kinetre or thermobyhamil 31H3Bet er all parts yeements that hae the ing hbreviated etrn urti 000
- 1. NaNH2: 2. CH;CH,CHO; 3. H*(quenching): 4. H/Pd/BaSO,/pyridine; 5. OsO,/H,O2 H =H он он он он но HO HO он он но но OH EQurston 18 Consuder the reatons shown. CI (8) t HCI cl + H2 What type of resction in it? Which is the corred product A,B or C? Name the first reactant the second reactont Name theR R 200 R H H [1] Nu: [2] H₂O R 'R' st ↓ X H₂SO4 CH3CH2OH NaNH, NaNH, (2 equiv.) NaNH, (2 equiw 1. NaCN 2. H₂O