Predict the starting alkyl bromide that would produce the product shown in the SN1 reaction. Assume no rearrangements. Stereochemistry is not considered. Draw Alkyl Bromide Reactant CH3CH2OH O
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- Plastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside the lenses that occurs when the lenses are exposed to sunlight. The original dye absorbs UV light but not visible light and is thus colorless, while the rearrangement product absorbs visible light and is thus darkened. (a) Show the mechanism of the rearrangement. (b) Why does the rearrangement product absorb at a longer wavelength (visible light) than the original dye (UV)?Give the major substitution product of the following reaction. a O CH3CO₂H Br heat CH₂ ? O There is no reaction under these conditions or the correct product is not listed here.2. Which of the following would give a meta product when submitted to EAS reaction conditions? OA OB OC OD OE OF A B C H CF3 E F CI HO
- Draw the mechanism ffrom benzaldehyde to this using: i)NaBH4 ii)TsCl, py iii)NaCN iiii)H+, H2ODraw a structural formula for the major organic product of the reaction shown below. & CH₂ (oran CH3CH₂O -CuLi 2 ether You do not have to consider stereochemistry. Sn [F ? ChemDoodle H3O +Q4. Provide reagents for the following transformations OH ов ОН ОН
- 4) Give the correct product with the correct stereochemistry. Me Me 5) Give the major product. hv HCI OCew fopics] Draw the major organic product of the reaction shown below. H2SO4 HO, • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. C opy aste [F ChemDoodle) Starting from benzent synthesigo the fo lloning compounds. çooH NO2 NO2 NO2 NO2 Br
- Synthesis: Give the correct starting material, reagents used or product as indicated. If you are not sure which one is being asked for, ask! Indicate stereochemistry where necessary. 1) 03 2) DMS 3) H₂O 1) 1 eq HCI 2) 1 eq HBr ?15)Draw the products of the reaCHon De l-hexyre utwith each of the follour d om 3HOissa aH20/2SO (HaS04macmods 9/0 1 RBH then OHH202 b Na NHz then CHs CH BrDraw the product formed from cyclohex-2-enone in each of three reactions. Reaction 1 Reaction 2 Reaction 1 1. NaCN 1. (CH3)2CuLi Reaction 2 product product 2. H3O*, H20 2. CH3CH21 A 1. EtO,CCH,CO¿Et NaOEt, HOET 2. Hао", Н-0, д Reaction 3 Reaction 3 product