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- 2. In the hydroboration/oxidation of the alkene below, two diastereomers are possible. Circle the one that would be the major product. 1. B₂H6 2. NaOH, H₂O₂ HO HO amani 2Draw the major organic product generated in the reaction below. Pay attention to Regio and stereochemical detail. a. HCI CH3OH CH 1. CH,CO,H 2. H*, H,O b.1. For each of the following pairs of Sy2 reactions, indicate which reaction occurs faster: a) CH3CH,Br + H0 OR CH,CH,Br + OH b) Remember the following is under an S2 condition: CH,CHCH,Br CH3 + OH CH;CH2CHBR + OH OR
- Give the major product(s) of the following reaction. Cro,CI он N. H. HO. OMe HO. H. There is no reaction under these conditions or the correct product is not listed here.3. Provide the product of the haloform reaction shown below, as well as a mechanism for its formation. 1. Br2, NaOH 2. H3O+Choose the reagent(s) that would be most likely to complete this reaction. I||| / A B C D 1. BH3-THF 2. H2O2, NaOH Br₂ H₂O OsO4 (catalytic) NMO RCO3H Done
- 3. CONCISELY explain why the following reaction would NOT work. Br CH₂ CH₂ SH 1.2 Li 2. CH3 CH3 -CH₂ 3. H3O+ work-up CH 3 CH3 HO CH₂ CH₂. CH₂ SH8. Circle the reactions that are synthetically useful (i.e.give only one major product). ~ Br₂, hv Cl₂, hv A NBS, hv NBS, hvWhat is/are the product(s) of this reaction sequence? 1. (CH3CH2)2NH, cat. HCI 2. NaBH3CN, EtOH 3. MCPBA 4. heat product(s) HO-N^ + CH2CH2 A + enantiomer B + (CH3)3N + (CH3)2NOH C D
- Draw the major organic product of the reaction shown below. HO. H2SO4 You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one.la . Rank the following substrates from most (1) to least reactive (3) in an Sn2 reaction. Explain the reason for your choice Br Br Br В A lb. Rank the following substrates from most (1) to least reactive (4) in an SN1 reaction. Explain the reason for your choice Br Br Br Br A B C Db).. .. Under each potential product of this E2 elimination, write "major product," "minor product," or "not formed." Me Br H Me Me OH Me Ph Ph H Me H Et Me Me Me Ph Ph Me Me Et