Please give the appropriate reagents to complete the following synthesis. 1 HO O O3/DMS Br2/hv O CH3B O AICI3/Cl2 1.. Li 2. Cul O HBr/H2O2 O EtOH O Br2/DCM O AICI3/CH3CI O Cl2/hv

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 29AP: Propose a pericyclic mechanism to account for the following transformation:
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Please give the appropriate reagents to complete the following synthesis.
1
2
HO
O3/DMS
Br2/hv
CH3B
AICI3/Cl2
1.. Li
2. Cul
HBr/H202
ELOH
Br2/DCM
AICI3/CH3CI
Cl2/hv
Transcribed Image Text:Please give the appropriate reagents to complete the following synthesis. 1 2 HO O3/DMS Br2/hv CH3B AICI3/Cl2 1.. Li 2. Cul HBr/H202 ELOH Br2/DCM AICI3/CH3CI Cl2/hv
NaOH, H20
H2/Pt
MeOH
Grubb's Catalyst
H20
HBr/H20
KMN04
Br2/H20
H2/Pd
HNO3/H2SO4
NaSH, DMSO
NaN3/CH3CN
heat
NaCN, DMF
LDA/DIPA
NBS
HBr/DCM
Transcribed Image Text:NaOH, H20 H2/Pt MeOH Grubb's Catalyst H20 HBr/H20 KMN04 Br2/H20 H2/Pd HNO3/H2SO4 NaSH, DMSO NaN3/CH3CN heat NaCN, DMF LDA/DIPA NBS HBr/DCM
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