pK, of NH, is 9.26. Hence, effective pH range for NH,OH-NH,Cl buffer is about :- (1) 8.26 to 10.26 (2) 4.74 to 5.74 (3) 3.74 to 5.74 (4) 8.26 to 9.26
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- Calculate the pH change that results when 11 mL of 5.1 M NaOH is added to 790. mL of each the following solutions. Use the Acid-Base Table. (a) pure water 4.0 5.84 (b) 0.10 M NH4CI 4.0 5.43 (c) 0.10 M NH3 4.0✔ X (d) a solution that is 0.10 M in each NH4+ and NH3 4.0✔Determine the pH during the titration of 62.0 mL of 0.342 M formic acid (K,- 1.8x104) by 0.342 M KOH at the following points. (Assume the titration is done at 25 °C.) (a) Before the addition of any KOH (b) After the addition of 15.0 mL of KOH (c) At the half-equivalence point (the titration midpoint) (d) At the equivalence point (e) After the addition of 93.0 mL of KOH7) The POH of a buffer solution that is 0.080 M aqueous HF acid and 0.042 M NH,F is: (K, of HF = 5.40 x 104) a) 11.0 b) 9.56 c) 2.99
- Calculate the pH change that results when 15 mL of 2.7 M HCI is added to 600. mL of each of the following solutions. Use the Acid-Base Table. (a) pure water 4.0 -5.82 (b) 0.10 M CH3COO- 4.0 4.43 (c) 0.10 M CH3COOH 4.0 X (d) a solution that is 0.10 M in each CH3COO and CH3COOH. 4.014) 40 ml of 0.0900 HCI is diluted to 100 ml with water and titrated with 0.1000M NAOH. Calculate the pH after the addition of the following volume (ml) of the titrant added: (a) 0.00 (b) 10.00 (c) 18.00 (d) 30.00 (e) 35.95 (f) 36.00 (g) 36.05 (h) 40.00Determine the pH during the titration of 67.0 ml of 0.375 M formic acid (K, - 1.8x10 4) by 0.375 M KOH at the following points. (Assume the titration is done at 25 °C.) (a) Before the addition of any KOH (b) After the addition of 17.0 ml of KOH (e) At the half-equivalence point (the titration midpoint) (d) At the equivalence point (e) After the addition of 101 mL of KOH Submit Show Appresch Show Tutar e
- A 93.0 mL sample of 0.0100 M HIO4 is titrated with 0.0200 M LIOH solution. Calculate the pH after the following volumes of base have been added. (a) 14.4 mL pH = 2.57 (d) 47.4 mL pH = X X (b) 44.2 mL pH = (e) 78.1 mL pH = X X (c) 46.5 mL pH = XCalculate the pH change that results when 15 mL of 2.0 M HCI is added to 580. mL of each of the following solutions (a) pure water 4.0-5.70 (b) 0.10 M CH3COO 4.04.28 (c) 0.10 M CH3COOH 4.0 (d) a solution that is 0.10 M in each CH3COO and CH3COOH. 4.0Addition of the indicator methyl orange to an unknownsolution leads to a yellow color. The addition of bromthymolblue to the same solution also leads to a yellow color.(a) Is the solution acidic, neutral, or basic? (b) What is therange (in whole numbers) of possible pH values for the solution?(c) Is there another indicator you could use to narrowthe range of possible pH values for the solution?
- Which solution is a buffer?(a) a solution that is 0.100 M in HNO2 and 0.100 M in HCl(b) a solution that is 0.100 M in HNO3 and 0.100 M in NaNO3(c) a solution that is 0.100 M in HNO2 and 0.100 M in NaCl(d) a solution that is 0.100 M in HNO2 and 0.100 M in NaNO2Calculate the number of grams of ammonium chloride that must be added to 2.00 L of a 0.500 M ammonia solution to obtain a buffer of pH = 9.20. Assume the volume of the solution does not change as the solid is added. Kb for ammonia is 1.80 * 10-5. (a) 60.7 g (b) 30.4 g (c) 1.52 g (d) 0.568 g (e) 1.59 * 10-5Ammonia is a convenient buffer system in the slightly basic range. (a) What is the pH of a buffer solution containing 24 g of NH4Cl dissolved in 1.00 L of 0.879 M NH3? pH = 9.5521 (b) How many moles of acid are required to change the pH of this solution by 0.06 pH units? i 0.23 pH = (c) Suppose 4.8 mL of 12.9 M HCI solution is added to 362 mL of the solution of Part (a). Calculate the new pH. mol i 9.08