pH of 0 unless otherwise indicated. Because it has caused confusion in the past, let me be clear. You are asked to draw a poutbaix diagram

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter15: Acid–base Equilibria
Section: Chapter Questions
Problem 82AP
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All reactions are at pH of 0 unless otherwise indicated. Because it has caused confusion in the past, let me be clear. You are asked to draw a poutbaix diagram for the table below.

You are asked to draw a poutbaix diagram for Sulfur from the data below.
Given Rxn data: Only use the given reaction data.
Reaction
E (V)
S+ H20 + 2 e = SH° + OH"
-0.478 pH = 14
%3D
S+ 2 H* + 2 e2 HS(ag)
0.142
S20g2 + 2 e=2 SO,²-
2.010
HSO3 + 5 H* + 4 e2S+ 3 H2O
0.480
SO32 + 6 H* + 4 e S+3 H2O
-0.658 pH =14
SO,2 + 4 H* +2 e2 H2SO3 + H2O
0.172
SOQ + H2O + 2 e SO3² + 2 °OH
-0.930 pH = 14
S2062 + 4 H* + 2 e° ² 2 H2SO3
0.564
2 SO,2 + 4 H* + 2 e°² S20g²² + H20
-0.22
Transcribed Image Text:You are asked to draw a poutbaix diagram for Sulfur from the data below. Given Rxn data: Only use the given reaction data. Reaction E (V) S+ H20 + 2 e = SH° + OH" -0.478 pH = 14 %3D S+ 2 H* + 2 e2 HS(ag) 0.142 S20g2 + 2 e=2 SO,²- 2.010 HSO3 + 5 H* + 4 e2S+ 3 H2O 0.480 SO32 + 6 H* + 4 e S+3 H2O -0.658 pH =14 SO,2 + 4 H* +2 e2 H2SO3 + H2O 0.172 SOQ + H2O + 2 e SO3² + 2 °OH -0.930 pH = 14 S2062 + 4 H* + 2 e° ² 2 H2SO3 0.564 2 SO,2 + 4 H* + 2 e°² S20g²² + H20 -0.22
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