p (atm) Q 10P 2 3 4 P. 0 T V (m³) 0 A Brayton-cycle heat engine with diatomic gas follows the cycle shown in Figure (1-2 and 3-4 are adiabatic processes). The heat input from the burning fuel is 2.06 MJ per cycle. Determine the engine's thermal efficiency (in percent) by explicitly computing the work done per cycle. P=1.03 atm, T₁ =363 K, V=1.46 m³.
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- The Carnot cycle is represented by the temperature-entropy diagram shown below. (a) How much heat is absorbed per cycle at the high-temperature reservoir? (b) How much heat is exhausted per cycle at the low-temperature reservoir? (c) How much work is done per cycle by the engine? (d) What is the efficiency of the engine?An ideal gas expands isothermally along AB and does 700 J of work (see below). (a) How much heat does the gas exchange along AB? (b) The gas then expands adiabatically along BC and does 400 J of work. When the gas returns to A along CA, it exhausts 100 J of heat to its surroundings. How much work is done on the gas along this path?A Carnot engine has an efficiency of 0.60. When the temperature of its cold reservoir the efficiency drops to 0.55. If initially Tc=27, determine (a) the constant value of Th and (b) the final value of Tc.
- Two hundred grams of water at 0 is brought into contact into thermal equilibrium successively with reservoirs at 20 , 40 , 60 , and 80 . (a) What is the entropy change of the water? (b) Of the reservoir? (c) What is the entropy change of the universe?When a gas expands along AB (see below), it does 500 J of work and absorbs 250 J of heat. When the gas expands along AC, it does 700 J of work and absorbs 300 J of heat. (a) How much heat does the gas exchange along BC? (b) When the gas makes the transmission from C to A along CDA, 800 J of work are done on it from C to D. How much heat does it exchange along CDA?(a) What is the hot reservoir temperature of a Carnot engine that has an eficiency of 42.0% and a cold reservoir temperature of 210C ? (b) What must the hot reservoir temperature be for a real heat engine that achieves 0.700 of the maximum eficiency, but still has an efficiency of 42.0% (and a cold reservoir at 27.0C )? (c) Does your answer imply practical limits to the efficiency of car gasoline engines?
- (a) On a winter day, a certain house loses 5.00108J of heat to the outside (about 500,000 Btu). What is the total change in entropy due to this heat transfer alone, assuming an average indoor temperature of 21.0C and an average outdoor temperature of 5.00C ? (b) This large change in entropy implies a large amount of energy has become unavailable to do work. Where do we find more energy when such energy is lost to us?Discuss the change in entropy of a gas that expands (a) at constant temperature and (b) adiabatically.The gasoline internal combustion engine operates in a cycle consisting of six parts. Four of these parts involve, among other things, friction, heat exchange through finite temperature differences, and accelerations of the piston; it is irreversible. Nevertheless, it is represented by the ideal reversible Otto cycle, which is illustrated below. The working substance of the cycle is assumed to be air. The six steps of the Otto cycle ale as follows: i. Isobaric intake stroke (OA). A mixture of gasoline and air is drawn into the combustion chamber at atmospheric pressure P0 as the piston expands, increasing the volume of the cylinder from zero to VA . ii. Adiabatic compression stroke (AB). The temperature of the mixture rises as the piston compresses it adiabatically from a volume VA to VB . iii. Ignition at constant volume (BC). The mixture is ignited by a spark. The combustion happens so fast that there is essentially no motion of the piston. During this process, the added heat Q1 causes the pressure to increase from pB to pc at the constant volume VB(=Vc) . iv. Adiabatic expansion (CD). The heated mixture of gasoline and air expands against the piston, increasing the volume from VC to VD . This is called the power stroke, as it is the part of the cycle that delivers most of the power to the crankshaft. v. Constant-volume exhaust (DA). When the exhaust valve opens, some of the combustion products escape. There is almost no movement of the piston during this part of the cycle, so the volume remains constant at VA(=VD) . Most of the available energy is lost here, as represented by the heat exhaust Q2 . vi. Isobaric compression (AO). The exhaust valve remains open, and the compression from VA to zero drives out the remaining combustion products. (a). Using (i)e=W/Q1; (ii)w=Q1Q2; and (iii)Q1=nCv(TCTB),Q2=nCv(TDTA), Show that e=1TDTATCTB. (b). Use the fact that steps (ii) and (iv) are adiabatic to show that e=11r1 where r=VA/VB . The quantity r is called the compression ratio of the engine. (c) In practice, r is kept less than around 7. For larger values, the gasoline-air mixture is compressed to temperatures so high that it explodes before the finely timed spark is delivered. This preignition causes engine knock and loss of power. Show that for r=6 and =1.4 (the value for air), e=0.51 , or an efficiency of 51%. Because of the many irreversible processes, an actual internal combustion engine has an efficiency much less than this ideal value. A typical efficiency for a tuned engine is about 25% to 30%.
- Consider the process shown below. During steps AB and BC, 3600 J and 2400 J of heat, respectively, are added to the system. (a) Find the work done in each of the processes AB, BC, AD, and DC. (b) Find the internal energy change in processes AB and BC. (c) Find the internal energy difference between states C and A (d) Find the total heat added in the ADC process. (e) From the information given, can you find the heat added in process AD? Why or why not?A Carnot engine employs 1.5 mol of nitrogen gas as a working substance, which is considered as an ideal diatomic gas with =7.5 at the working temperatures of the engine. The Carnot cycle goes in the cycle ABCDA with AB being an isothermal expansion. The volume at points A and C of the cycle are 5.0103 m3 and 0.15 L, respectively. The engine operates between two thermal baths of temperature 500 K 300 K. (a) Find the values of volume at B and D. (b) How much heat is absorbed by the gas in the AB isothermal expansion? (c) How much work is done by the gas in the AB isothermal expansion? (d) How much heat is given up by the gas in the CD isothermal expansion? (e) How much work is done by the gas in the CD isothermal compression? (f) How much work is done by the gas in the BC adiabatic expansion? (g) How much work is done by the gas in the DA adiabatic compression? (h) Find the value of efficiency of the engine based on the net and heat input. Compare this value to the efficiency of a Carnot engine based on the temperatures of the baths.Of the following, which is not a statement of the second law of thermodynamics? (a) No heat engine operating in a cycle can absorb energy from a reservoir and use it entirely to do work, (b) No real engine operating between two energy reservoirs can be more efficient than a Carnot engine operating between the same two reservoirs, (c) When a system undergoes a change in state, the change in the internal energy of the system is the sum of the energy transferred to the system by heat and the work done on the system, (d) The entropy of the Universe increases in all natural processes, (e) Energy will not spontaneously transfer by heat from a cold object to a hot object.