Oxidation of glucose using Benedict's or Barfoed's reagent results in a mixture of compounds including a glycolic acid (2 carbons) and erythronic acid (4 carbons). Identify the carbon-carbon bond that is broken in glucose (shown below) to yield these two acids (following further oxidation) and draw "electron pushing arrows" to indicate the electron source and electron sink involved in breaking this bond OH OH HO `H OH OH

Chemistry: Principles and Reactions
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ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter22: Organic Chemistry
Section: Chapter Questions
Problem 41QAP: Maleic acid and fumaric acid are the cis- and trans- isomers, respectively, of C2H2(COOH)2, a...
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Oxidation of glucose using Benedict's or
Barfoed's reagent results in a mixture of
compounds including a glycolic acid (2
carbons) and erythronic acid (4 carbons).
Identify the carbon-carbon bond that is
broken in glucose (shown below) to yield
these two acids (following further oxidation)
and draw "electron pushing arrows" to
indicate the electron source and electron
sink involved in breaking this bond
OH
OH
HO,
`H.
OH
OH
Transcribed Image Text:Oxidation of glucose using Benedict's or Barfoed's reagent results in a mixture of compounds including a glycolic acid (2 carbons) and erythronic acid (4 carbons). Identify the carbon-carbon bond that is broken in glucose (shown below) to yield these two acids (following further oxidation) and draw "electron pushing arrows" to indicate the electron source and electron sink involved in breaking this bond OH OH HO, `H. OH OH
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