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- Fe+3 (aq) + SCN – (aq) FeSCN +2 (aq) She mixes 4.00 mL of 2.00 mM SCN– and 5.00 mL of 2.00 mM Fe+3 ions, then diluting with 1.00mL of water to give a total volume of 10.00mL. She measures the absorbance of the solution asbeing 0.210. If she has previously calculated the molar absorbtivity constant (ε) of the product tobe 2583 cm–1 M–1, what is her best estimate for the K value for this reaction?Ksp for Co(OH)2 is 5.92x10^-15A student prepared four standard solutions of (NH4)2Fe(SO4)2 and measured their absorbance at 505 nm. She created a calibration plot with the best-fit line of y = 9372 x + 0.0539. She measured the absorbance of her diluted unknown sample solution as (4.69x10^-1) nm. If she prepared her diluted sample solution by diluting 10.00 mL of the original solution to a total volume of 50.00 mL with deionized water, what is the concentration of Fe2+ in her original solution? Answer in units of M. Note: Your answer is assumed to be reduced to the highest power possible.
- The standard curve was made by spectrophotographic analysis of equilibrated iron(III) thiocyanate solutions of known concentration. You are asked to analyze a Fe(SCN)2+ solution with an unknown concentration and an absorbance value of 0.392. The slope-intercept form of the equation of the line is y = 4538.1x +0.0077. The unknown was analyzed on the same instrument as the standard curve solutions at the same temperature. What is the Fe³+ concentration of the unknown solution? [Fe³+] = mol/L Absorbance Iron(III) thiocynate standard curve 1.0 V 0.5 0.0001 Fe³+ concentration (M) 0 0.0002A student measures k for a certain blue dye to be 400.4 M-1 at 560 nm. What is the molarity of the dye in a solution with an absorbance of 0.118 at this wavelength?Blue Blue dye stock solution 0.293 M Absorbance at 630 nm 0.00265 Calibration curve y = 0.0833x A solution is prepared by diluting 2.81 mL of the blue dye stock solution to 25.00 mL. The measure absorbance for the prepared solution is listed in the data table. (a) What is the theoretical molar concentration? [Blue]theoretical | × 10 |M (b) What is the experimental molar concentration? [Bluelexperimental x 10 M (c) What is the percent error? Percent error (blue) =
- 7. A Cu2* solution obtained by dissolving a 3.1871-g penny in 500 mL of nitric acid has an absorbance of 0.342 at 620 nm in a 1.00 cm cell. The calibration curve prepared from Cu2+ solutions of varying concentrations has a slope of 281.8 L/mol and a y-intercept of 0.0106. (a) Calculate the concentration of the solution in moles per liter. (b) Calculate the percent Cu by mass in the penny(d) 3-13. Distis me Jum 4 A method of analysis yields weights for gold that are low by 0.4 mg. Calculate the caused by this uncertainty if the weight of gold in the sample is (a) 900 mg. (c) 150 mg. 1-7. The method described in Problem 3-6 is to be used for the analysis of ores that assay about 1.2% gold. What minimum sample weight should be taken if the relative error resulting from a 0.4-mg loss is not to exceed -0.2%? percent relative error (a) (b) (b) 600 mg. (d) 30 mg. 3-14. Wha stan stam 3-15. Сог mea (b) -0.5%? (a) -0.8%? (c) (d) 1.2%? 3.5 3-8. The color change of a chemical indicator requires an overtitration of 0.04 mL. Calculate the percent relative error if the total volume of titrant is (a) 50.00 mL. (c) 25.0 mL. 3-9. A loss of 0.4 mg of Zn occurs in the course of an analysis to determine that element. Calculate the per- cent relative error due to this loss if the weight of Zn in the sample is (a) 40 mg. (c) 400 mg. 3.1 3.1 (b) 10.0 mL. 3.3 2.5 (d) 40.0 mL. Fo (a (E (b) 175…4= An ion with a charge of +3 is accelerated into the 1.79 m flight tube of a linear time-of-flight (TOF) mass spectrometer with an acceleration voltage of 20.0 kV. It takes the ion 74.4 us to reach the detector. What is the mass (m) of the ion? Gives
- A plot of Absorbance vs. molarity of Fe(SCN)2+ from part one of the lab gives a straight line with the following equation. y = 51x R2 = 0.998 If a student measures an absorbance value of 0.375 in the second part of the lab, what is the molarity of Fe(SCN)2+ in this solution?The table below describes a procedure in preparing standard solutions of a protein sample with different concentrations. (A) Determine the concentrations of each tube if the starting concentration of the protein is 500 mg mL (B) Determine the equation of the line if the concentration (x-axis) was plotted vs the absorbance (y-axis). (C) What is the concentration, in mg mL, of the diluted unknown protein sample if the absorbance at 595 nm is 0.333? L-1. Tube Volume of protein, Volume of water, Final concentration, Absorbance #3 mL mL (at 595 nm) mg mL-1 0.00 5.00 0.113 12 0.70 4.30 0.184 3 1.40 3.60 0.251 14 2.10 2.90 0.329 15 2.80 2.20 0.385 3.50 1.50 0.454 17 4.20 0.80 0.503 8 5.00 0.00 0.577 Suppose that the unknown protein (diluted) sample in 4.C was diluted from a protein stock solution. Determine the concentration of the original unknown protein stock solution if 2.00 mL of the protein solution was mixed with 8.00 mL of water to create the unknown protein (diluted) sample in 4.C.Write the chemical formula for tin(II) chloride dihydrate |2+ 3+ 4+ + 1 3 4 7 8 9. O3 O5 O8 (1) (g) (aq) Sn Sb Са Ti Tn CI C Ch + • æ H¸O Delete Reset CO 2. 3. 4- 2. 2.