-OH R Water RCOO- Na+ layer RCOOH Add aq. NaHCO; RNH, Ether -HO- layer R R-C-R' RNH, (Dissolved in ether) R-C-R' Add aq. NaOH Ether Water layer layer Ether R-C-R' layer RNH, Add O- Na+ aq. HCI R Water R-C-R' R-NH,+ CI layer 2 Figure 12.10 Separating a four-component mixture by extraction.

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter11: Solutions And Colloids
Section: Chapter Questions
Problem 27E: What is the microscopic explanation for the macroscopic behaviour illustrated in Figure 11.15?
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Aqueous hydrochloric acid was used after the sodium bicarbonate and sodium hydroxide extractions in the separation scheme shown in Figure 12.10. Is it possible to use this reagent earlier in the separation scheme to achieve the same overall result? If so, explain where you would perform this extraction.

-OH
R
Water
RCOO- Na+
layer
RCOOH
Add aq.
NaHCO;
RNH,
Ether
-HO-
layer
R
R-C-R'
RNH,
(Dissolved
in ether)
R-C-R'
Add
aq. NaOH
Ether
Water
layer
layer
Ether
R-C-R'
layer
RNH,
Add
O- Na+
aq. HCI
R
Water
R-C-R'
R-NH,+ CI
layer
2
Figure 12.10
Separating a four-component mixture by extraction.
Transcribed Image Text:-OH R Water RCOO- Na+ layer RCOOH Add aq. NaHCO; RNH, Ether -HO- layer R R-C-R' RNH, (Dissolved in ether) R-C-R' Add aq. NaOH Ether Water layer layer Ether R-C-R' layer RNH, Add O- Na+ aq. HCI R Water R-C-R' R-NH,+ CI layer 2 Figure 12.10 Separating a four-component mixture by extraction.
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9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax