О oints) Which of the following is a species that appears in the second step of the mechanism of the reaction after formation of the hydronium ion? H3C-CH2 H2SO4 H₂O C=CH2 H3C-CH2 H3C CH2 + C -CH3 H3C-CH2 H3C CH2 H H + O CH3 H3C CH2 H3C-CH2 H CH-CH2 H3C CH2 + H H3C-CH2 OH CH3 H3C CH₂
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- The plot below shows the number of collisions with a particular energy for two different temperatures. a. Which is greater, T2 or T1? How can you tell? b. What does this plot tell us about the temperature of the rate of a chemical reaction? Explain your answer.2NO2(g) + F2(g) -> NO2F(g) H°rxn = -284 kJ/molrxn NO2(g) and F2(g) can reactto produce NO2F(g), as represented above. A proposed mechanism for the reaction has two elementary steps, as shown below. Step 1: NO2 + F2 -> NO2F + F (slow) Step 2: NO2 + F -> NO2F (fast) a.) Write a rate law for the overall reaction that is consistent with the proposed mechanism. b.) On the incomplete reaction energy diagram below, draw a curve that shows the following two details. The relative activation energies for the two elementary steps The enthalpy change of the overall reaction Can all of them be solved please, and thank you very much!In a hydrocarbon solution, the gold compound (CH3)3AUPH3 decomposes into ethane (C2H6) and a different gold compound, (CH3)AUPH3. The following mechanism has been proposed for the decomposition of (CH3)3AUPH3: Step 1: (CH3)3 AuPH; (CH3);Au + PH3 (fast) Step 2: (CH3)3 Au 4, C,H, + (CH;)Au (slow) Step 3: (CH3)Au + PH3 (CH3)AUPH3 (fast) (a) What is the overall reaction? (b) What are the inter- mediates in the mechanism? (c) What is the molecular- ity of each of the elementary steps? (d) What is the rate- determining step? (e) What is the rate law predicted by this mechanism? (f) What would be the effect on the reac- tion rate of adding PH3 to the solution of (CH3)3AUPH3?
- What will the intermediate form of this molecule be after an intramolecular Sn2 attack? \N- (a) CI -NⓇ CI CI CI -CI (b) CI CI 27 (c) متر CI (d) CI NThe following initial rate data are for the reaction of tertiary butyl bromide with hydroxide ion at 55 °C: (CH3)3CB + OH → (CH3)3COH + Br Experiment [(CH3)3CB1],, M [OH], M Initial Rate, Ms-1 1 0.890 1.50x10-3 1.50x10-3 3.01x10-3 3.01x10-3 0.118 0.118 2 1.78 0.890 1.78 3 0.237 4 0.237 Complete the rate law for this reaction in the box below. Use the form k[A]j™[B]" , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant isConsider the following reaction for question #1 - #3 What is/are the most likely mechanism/s for the following reaction? SN1 OSN2 E1 E2 CH3CH₂OH
- what is the mechanism of reaction с CH 5 mol % Cu(acac) CH₂ + N₂C(CO₂C₂Hs)2 N CH=CH2 -CO₂C₂H N CO₂C₂H CH CH₂ 98%2ClO2(aq) + 2OH-(aq) ClO3-(aq) + ClO2-(aq) + H2O(l) The above reaction was studied (at a particular temperature) and the following data (for rate = -d[ClO2]/dt) were obtained: [ClO2]0 [OH-]0 Initial Rate (mol/L) (mol/L) (mol L-1 s-1) 0.170 0.170 1.43 0.340 0.085 2.87 0.340 0.170 5.74 hello, i am confused about the order of clo2 given the data above. When 1 use rate 1 and 2 given thier respective clo2 intial concentrations, i get first order for clo2, but when i use rate 1 and rate 3 and thier respective clo2 intial concentrations, i get an order of 2 for clo2. so which order is correct for clo2 given this data? first order or second order?HSO3¯(aq) + H202(aq) → HSO, (aq) + H20(l) The mechanism is given below, k1 HSO3¯(aq)+ H202(aq) S0200H¯(aq) + H20(1l) k-1 k2 SO200H-(aq) + H30*(aq) 3 HSO, (aq) + H30*(aq) (fast) a) Which is the reactive intermediate? b) Make a steady-state approximation for the reactive intermediate concentration c) Express the rate of formation of HSO 4(a9) in terms of the concentrations of HSO 3(aq), H2O2(39) and H30*(ag)
- The following initial rate data are for the reaction of tertiary butyl bromide with hydroxide ion at 55 °C: (CH3)3CB + OH (CH)3COН + Br Experiment [(CH3)3CB1],. M [OH], M Initial Rate, Ms1 6.64x10-3 6.64x10-3 1.33x10-2 1.33x10-2 1 0.540 0.408 0.540 0.816 1.08 0.408 1.08 0.816 Complete the rate law for this reaction in the box below. Use the form k[A]"[B]" , where 'l' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant isIdentify the type of elementary step. H O coordination -CH3 O bimolecular elimination O bimolecular substitution O nucleophile eliminationThe second-order rate constant for the reaction CH3COOC2H5(aq) + OH-(aq)→ CH3CO2-(aq) + CH3CH2OH(aq) is 0.11 dm3 mol-1 s- 1. What is the concentration of ester after(a) 15 s, (b) 15 min when ethyl acetate is added to sodium hydroxide so that the in it ial concentrations are [NaOH] 0.055 mol dm-3 and [CH3COOC2H5] = 0.150 mol dm-3?