o-Bromopropylbenzene Complete the scheme by dragging the labels to the appropriate targets. Note: not all labels will be used. H₂ Pd/C Br Br Br FeBr 1. CHÍCH CÓC AIC 2. HO CH.CH,CH,CI AICI Br Br Reset Help
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- Drag the appropriate labels to their respective targets. Note: not all labels will be used. pK. <0 pK. ~ 5 pK. ~ 10 CH;CH,CH,NH2 CH3CH2CH2OH CH3CH2COOH CH;CH2CH,NH3 pK. ~15 pK. ~ 40Which synthetic route(s) would complete the reaction shown? Br || ||| I and II O I and III ? HO OH + enantiomer Synthesis I: 1. NaCCCH3; 2. Na/NH3(I) ;3. OsO4; 4. NaHSO3, H₂O Synthesis II: 2. NaCCCH3; 2. H2, Lindlar's catalyst; 3. MCPBA; 4. aq. H₂SO4 Synthesis III: 1. NaCCCH3; 2. H₂, Pt; 3. MCPBA; 4. aq. H₂SO4Identify whether the following mechanism is SN1, SN2, E1, E2, or E1cB or a combination. a. b. C. d. Br benzyl bromide Br benzyl bromide NaOEt in dry alcohol water in formic acid solution 3-iodocyclohexan-1-one 1-iodo-2,2-dimethylbutane NaOEt in EtOH Aa NaSCH3 OH E
- Dtermine the reagents that can accomplish the rxn CH2OH (1) Reagent ? (2) Reagent ? C9H1202 (4) Reagent ? (3) H+ a. (1) SOC12 (2) 1-propanol; (4) PCC/pyridine b. (1) NaH, (2) acetone, (4) NABH4 c. (1) NaH, (2) epoxide (4) PCC/pyridine d. (1) Jones reagent, (2) NaH, (4) epoxideWhat is the expected major product for the following reaction? O IV I OCH 3 |||||... + enantiomer || 1. Hg(OAc)2, CH3OH 2. NaBH4 НО. OH ... H3CO. + enantiomer ||| IV H3CO VGiven each of the acid/base equilibria shown, provide curved arrows that represent the reaction mechanism. Also, calculate the Keq value for each. a. b. H ہم H -H H-O-CH3 LDA G + + ноо HO ΝΗ
- (BUOK (BUOH, heat d. (BUOH, heat EESH e minimum temp NaCN Br acetone minimum temp EISH Br minimum temp 5. Mechanisms. Give the mechanism for each rx above as indicated. Use additional sheets as needed. c. (rx 4c) f. (rx 4f) g. (rx 4g) DELLThe answer to this question is D, can you please draw the mechanism to get that product? 1. -MgBr H;0* workup ? OTMS 2. TBAF 3. POCI, / pyridine (еxcess) 4. Нeat он A B он CI CI DDetermine the mechanism of nucleophilic substitution of each reaction and draw the products, including stereochemistr CH₂CH3 CI Br + CN d. + CH3COOH a. acetone + -OCH3 e. DMF f. b. C. ||||| a ||||| Br H Br CH2CH2CH3 + CH3OH DMSO H CH3 CI Br + OCH₂CH3 + CH3CH₂OH
- The major product of the given reaction has the molecular formula CoH0,. Draw its structure in the most stable 10*16 tautomeric form. Select Draw Rings More Erase my 1. NaOCH,CH, 2. H,O CH,CH,OH3. Provide the mechanism for the following rxn: ethanol heat Br a. CH3 CH3 NAOCH3, CH3OH Br b. D H OH H,SO4 с.Which are the best reagents for the rxn ċ– CH3 First Step CH2 - N H Second Step `CH2CH3 Third Step a. first step (i)LIAIH4/ether,(ii) H2O/base; second step CH3CH2NH2/H+; third step Acetic anhydride/pyridine b. first step H2/Pt; second step CH3CH2NH2/H+; third step Acetic anhydride/pyridine c. first step CH3CH2NH2/H+; second step) (i)LiAlH4/ether, (ii) H2O/base; third step Acetic anhydride/pyridine d. first step NaCN/alcohol; second step i. LİAIH4/ether, ii. H2O/base; third step Acetic anhydride/pyridine