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- I. Complete the reaction map below А. HO HO 2 H2/Pt cold KMNO4 3 CkWhat is the missing reactant in the following reaction? ? NaOC2H5 H* OCH5 HOC2H5 || C2H50 H. IV II C2H50 OC H5 H H. Select one: А. I В. II C. II D. IVMg. Et0 OH ? 7. OH NH pyridinium chlorochromate ? dichloromethane as a solvent 1. ? 2. ? OH ? 2. H,O+ 10.
- 7. Reaction Scheme. о А N 1. xs Mel, xs K2CO3 2. Ag2O, H₂O 3. heat NH2 NH2 or two differnet methods (no same steps/reagents) C5H12N2 Br2, xs NaOH, xs H₂O OHC 1.03 2. DMS CHOi. Which of the reactions given below is wrong? H3O*/H20 (A) MgBr + CO2 H2/Pt (B) CH;CH2CN CH;CH,NH2 heat NABH4 (C) HO OH/H20 (D) CI OHOH SYNTHESIS 1. POCI3 2. HBr, ROOR 3. Mg, ether 4. benzaldehyde 5. H3O+ workup 6. PCC 7. CH3MgBr 8. H3O+ workup Br T
- 3. What is the major organic product of the following reaction? I. II. III. CH=CH₂ CH₂CH3 CH₂CH3 CH=CH₂ IV. H₂ Pt ? CH=CH₂ CH=CH₂ A. I B.II C.III D.IV E. V 4. Which of the following can be reduce by H2/Ni? O O || A. CH3-C-OH B. CH3-C- O || OCH 3 C. CH3-C NHCH3 D. CH3-C-C1 E. CH3-C-NH2 5. Which of the following reagents would reduce carboxylic acids and esters into alcohols? A. H2/Ni B. 1. LiAlH4/2. H+ C. Na/NH3 D. 1.NaBH4/2. H+ E. Zn(Hg)/HC116. Fill in the blanks in the reactions below 1.03 2. Me₂S 1.03 2. H₂O₂ 20 Three (3) Products 1. BH3, THF/H₂O 2. H₂O2, NaOH 1. Hg(OAc)2/H2O 2. NaBH4 2 HO. H CHEM 241-Group10.3. What is the major organic product of the following reaction? I. II. III. A. CH=CH₂ CH₂CH3 CH CH₂CH3 CH=CH₂ IV. H₂ Pt ? CH=CH₂ CH=CH₂ A. I B. II C. III D. IV E. V 4. Which of the following can be reduce by H2/Ni? O O O O || COH B. CH3-C OCH 3 C CH3-C NHCH 3 D. CH3-C-C1 E. CH3-C 5. Which of the following reagents would reduce carboxylic acids and esters into alcohols? A. H2/Ni B. 1. LiAlH4/2. H+ C. Na/NH3 D. 1.NaBH4/2. H+ E. Zn(Hg)/HCl -NH2
- 3. Draw the major product to each of the following reactions. a. b. C, d. e. H₂O HCI H₂SO4, HgSO4 Na, NH3 H₂ Lindlar's catalyst -78°C Pd/C H₂compound d NaCN, SN2 compound f compound c Reagents HBr 2 equivalents of NaNH2 H2, Lindlar's catalyst Na / NH3 H2SO4, H9SO4 NaCN, SN2 m. a. b b. HBr, H2O2, hy n. c. H2O, H2SO4 d. Br2 O. compound b compound e р. е. Cl f. Н2. Pd (sia)2BH then H2O2, NaOH 1 equivalent of NaNH2 q. r. g. Br2, H2O S. NBS, hv compound a h. Cl2, H2O i. t. Br2, hv OsO4 then NaHSO3 Cl2, hv u. j. Hg(OAc)2, H20 then NaBH4 HCI V. k. BH3 then H2O2, NaOH Og then (CH3)2S w. (CH3);CO"K* I. The above synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. In this synthesis, reagents from the table are used to carry out the indicated steps (shown in blue). In the box below, draw the structure of compound e. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If there are alternative structures, draw the most stable one. • If the reaction produces a racemic mixture, draw both stereoisomers. Separate structures with + signs from the drop-down menu.File Edit View History Bookmarks Profiles Tab Window Help Aktiv Chemistry app.101edu.co esc ! 1 Compound 1 OH OH Q Compound 3 @ 2 X + 1. BH3 2. NaOH/H₂O2 dria W 1,502 3 ? OH Compound 2 Compound 4 E Select the major product for the reaction shown below. OH ali $ 4 JUN 30 R 000 % 5 T 著 < 6 121 MacBook Pro Y & PAGES 7 W U A) Compound 1 B) Compound 2 C) Compound 3 D) Compound 4 8 1 DA ( 9 wwws 0 0 F