Methods of Spectrophotometric Titration Coulometry Potentiometry Job's Plot Yoe and Jones Method Mole Ratio Continuous Variation Slope Ratio Neutralization
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Q: If 26.98 mL of a standard 0.1650 M NaOH solution is required to neutralize 30.41 mL of H2SO4, what…
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Q: Provide proper IUPAC name for the following compound:: S
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Q: What is the major product of this Michael reaction? i A B. 1. NaOH 2. 3. H₂O* O Le C. D.
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Q: Absorbance 14 1.2 1 0.8 0.6 0.4 0.2 Curve 1 Curve 2 Curve 3
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- The following data are obtained from three standard soltions using UV-Vis spectroscopy: What is the colar concentration (M) of an unknown solution with an absorbance of 0.180 at 255 nm? The unknown solution contains the same analyte as the standard solution does. The molar mass of the analyte is 188.65 g/mol a) 4.82x10-5b)1.9x10-3c)3.60x10-4d)1.9x10-5e)1.8x 10-4Differentiate between qualitative analysis and quantitive analysis?The acid-base indicator HIn undergoes the following reaction in dilute aqueous solution: HIncolor1H++Incolor2 The following absorbance data were obtained for a 5.00 I0-4 M solution of HIn in 0.1 M NaOH and 0.1 M HC1. Measurements were made at wavelengths of 485 nm and 625 nm with 1.00-cm cells. 0.1 M NaOH A485 = 0.075 A625 = 0.904 0.1 M HC1 A485 = 0.487 A625 = 0.181 In the NaOH solution, essentially all of the indicator is present as In-; in the acidic solution, it is essentially all in the form of HIn. (a) Calculate molar absorptivities for In- and HIn at 485 and 625 nm. (b) Calculate the acid dissociation constant for the indicator ¡fa pH 5.00 buffer containing a small amount of the indicator exhibits an absorbance of 0.567 at 485 nm and 0.395 at 625 nm (1.00-cm cells). (c) What is the pH of a solution containing a small amount of the indicator that exhibits an absorbance of0.492 at 485 nm and 0.245 at 635 nm (1.00-cm cells)? (d) A 25.00-mL aliquot of a solution of purified weak organic acid HX required exactly 24.20 mL of a standard solution of a strong base to reach a phenolphthalein end point. When exactly 12.10 mL of the base was added to a second 25.00-mL aliquot of the acid, which contained a small amount of the Indicator under consideration, the absorbance was found to be 0.333 at 485 nm and 0.655 at 625 nm (1.00-cmcells). Calculate the pH of the solution and Ka for the weak acid. (e) What would be the absorbance of a solution at 485 and 625 nm (1.50-cm cells) that was 2.00 10-4 M in the indicator and was buffered to a pH of 6.000?
- H4)ConsiteR the following Beaction: Pa,t 8 H,0→ Hy POqt 3 HCl IP 12.49 of | 10.09 of Hy O, what is the limiting Ctrl PCI, is PeacteD witn T0.0g Peactant ? Molar nhass of Pelg: 137.329/mel. holarmass of HoO=18:0291 mel malar mass of Hy POz =¢2.00 glmol molar mass of HCl= 35.4A16 glmel. %3D0 The acid-base indicator HIn undergoes the following reaction in dilute aqueous solution:HIn color1 m H1 1 In2color2The following absorbance data were obtained for a 5.00 3 1024M solution of HIn in 0.1 M NaOH and0.1 M HCl. Measurements were made at wavelengths of 485 nm and 625 nm with 1.00-cm cells.0.1 M NaOH A485 5 0.075 A625 5 0.9040.1 M HCl A485 5 0.487 A625 5 0.181In the NaOH solution, essentially all of the indicator is present as In2; in the acidic solution, it is essentiallyall in the form of HIn.(a) Calculate molar absorptivities for In2 and HIn at 485 and 625 nm.(b) Calculate the acid dissociation constant for the indicator if a pH 5.00 buffer containing a small amountof the indicator exhibits an absorbance of 0.567 at 485 nm and 0.395 at 625 nm (1.00-cm cells).(c) What is the pH of a solution containing a small amount of the indicator that exhibits an absorbance of0.492 at 485 nm and 0.245 at 635 nm (1.00-cm cells)?(d) A 25.00-mL aliquot of a solution of purified weak…A chromatogram of a mixture of species A, B, and C provided the following data: a) Define "Retention time". b) Calculate the resolution between species A and B. c) Calculate the retention time of species B necessary to separate it from species A with a resolution of 1.5.
- A method of quantitative determination of the concentration of constituentsof a sample analyzed by gas chromatography is area normalization. Thiscomplete elution of all sample constituents is required. Thearea of each peak is measured and corrected for the detector response to the diffe- renteseluatos. This correction involves dividing the area by an empiricalcorrection factorDetermined. The concen ration of the analyte is found from the ratio between itscorrected and the total corrected area of all peaks. For a chromatogram containing threerelative areas were determined as 16.4; 45,2; and 30.2, in the order ofincreased retention time. Calculate the percentage of each compound if therelative responses from the detector are 0.65, 0.73 and 0.85, respectively.Create a separations flowchart for qualitative analysis for the following Sb3+ Fe3+ Zn2+ Al3+ Cd2+1) Study the chromatograph (below) of a mixture of Compounds A and B, run on the GCs in the teaching labs at CU Boulder. Compound A has the shorter retention time. STAAT 61 1.11 227 RT TYPE AREA XXXX XXXX XXXX AREAS 0.009 55874 44.117 ARIHT 0.61 XX XX XX 1.11 2.27 XX XX XX TOTAL AREA=XX MUL FACTOR=XX 1. What is the retention time of compound A? Compound B? 2. Which compound is present in a larger amount? 3. Which compound has the lower boiling point? 4. What would happen to the retention times of compounds A and B if the column temperature were raised? 5. You suspect that compound B is octane. What can you do to provide supporting evidence for this hypothesis?
- How is spiking used in qualitative analysis? Why are several different types of columns necessary to make a convincing case for the identity of a compound?auDUIUance UI U.I JU ai 4JJ IIII III 1. UU CIII cuvclic. Calculate the molar absorptivity of the pigment at 453 nm? Q5) A student is tasked to determine the number of moles of H2SO4 (aq) in a 200 ml of an unknown solution. The student prepares a series of solutions with known concentrations of H2SO4 (ag) and measures the absorbance of each at an appropriate wavelength. These data are used to construct the calibration plot shown below. 1.00 0.80- 0.60 - 0.40- 0.20- 0.00- 3 x 10-4 6 x 10-4 Concentration (mol/L) If the absorbance of the unknown solution is 0.70, how many moles of H2SO4 (aq) does the 200 ml sample contain? AbsorbanceFollowing titration analysis, a sample of a fruit juice was found to contain 8.9 mg cm-3 ascorbic acid. Given that the Mr value for ascorbic acid is 176.1 Da, calculate the value of the ascorbic acid concentration expressed in units of mmols dm-3 then enter it