Home - Profession...A mixture of nitric and sulfuric acids generates thenitroniium ion, *NO2 (mechanism provided), whichcan react with benzene to form nitrobenzene viaelectrophilic aromatic substitution. Using theprovided mechanism that forms the nitronium ion,give a full curved-arrow pushing mechanism for thereaction shown below, indicate the Lewis andEnroll EBronsted acids/bases at each step as appropriate(LA, LB, BA, BB) and include all important resonancecontributors at any ionic intermediates.To preview the image click here: OH:O-N+"-S-OHHNO3H2SO4OH2NO2+O=N=O + HSOnitronium ionelectrophile

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Answered: Home - Profession... A mixture of…

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter23: Amines

Section: Chapter Questions

Problem 23.31P

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Provide detailed (arrow pushing) mechanism for the following reaction. Whereappropriate indicate Lewis acid and base for each step, and whether they are alsoBronsted acids and bases (LB/BA, LA/BA etc.) Indicate the number of steps in themechanism and the number of intermediates.
A mixture of nitric and sulfuric acids generates the nitronium ion, + NO2 (mechanism provided, which can react with benzene to form nitrobenzene vin electrophilic aromatic substitution. Using the provided mechanism that forms the nitronium ion, give a full curved - arrow pushing mechanism for the reaction shown below, indicate the Lewis and Bronsted acids/bases at each step as appropriate (LA LB, BA, BB) and include all important resonance contributors at any ionic intermediates. :PH O-N+ неё он HNO3 H₂SO4 NO2 O=N=O + HSO nitronium ion electrophile
A mixture of nitric and sulfuric acids generates the nitroniium ion, +NO₂ (mechanism provided), which can react with benzene to form nitrobenzene via electrophilic aromatic substitution. Using the provided mechanism that forms the nitronium ion, give a full curved-arrow pushing mechanism for the reaction shown below, indicate the Lewis and Bronsted acids/bases at each step as appropriate (LA, LB, BA, BB) and include all important resonance contributors at any ionic intermediates. To preview the image click here : OH O-N+ S-OH HNO3 H₂SO4 OH₂ NO₂ O=N=O + HSO4 nitronium ion electrophile
A mixture of nitric and sulfuric acids generates the nitronium ion,+NO2 (mechanism provided, which can react with benzene to form nitrobenzene vin electrophilic aromatic substitution. Using the provided mechanism that forms the nitronium ion, give a full curved-arrow pushing mechanism for the reaction shown below, indicate the Lewis and Bronsted acids/bases at each step as appropriate (LA LB, BA, BB) and include all important resonance contributors at any ionic intermediates.
Rank the molecules in decreasing (strongest to weakest) acidity. Include ALL resonance structures with arrows and explain reasoning for rank.
Provide detailed (arrow pushing) mechanism for the following reaction, draw all importantresonance structures for the intermediates. Where appropriate indicate Lewis acid and base foreach step, and whether they are also Bronsted acids and bases (LB/BA, LA/BA etc.) Indicate thenumber of steps in the mechanism and the number of intermediates.
Checking my answer, there was difference with solution. (organic chemistry smith 5th ed 2.47P (d)) Solution said 'the acid base reaction between pentyne and ammonia is product way because pka of pentyne is 25, ammonia is 38 so pentyne will be deprotanted by ammonia.' but I think (and as written in the book) NH4+ is stronger acid than pentyne and acid-base reaction works when reactant is stronger acid than product conjugate acid. It isn't match that pentyne makes NH4+. who is incorrect?
Identify the stronger and weaker Bronsted acid, assign the smaller and largerpKa, identify the stronger and weaker Bronsted conjugate base give an explanation thatincludes resonance contributors if relevant.
Give the currved arrow pushing mechanism for the following reaction, indicate Lewis acid/base and Bronsted acid/base at each step as appropriate (LA, BA, LB, BB) and include all important resonance contributors of any ionic intermediates. To preview the image click here HCI (cat.) + HO heat
12) Rank these hydrogens as to acidity.
Give the currved arrow pushing mechanism for the following reaction, indicate Lewis acid/base and Bronsted acid/base at each step as appropriate (LA, BA, LB, BB) and include all important resonance contributors of any ionic intermediates. To preview the image click here HCI (cat.)
4. How can you differentiate basicity of aniline, ammonia, dimethylamine, methylamine

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