he lowest electronic levels for 14N 160 have the following characteristics: Calculate, for 5000 k, using statistics. A) The fraction of molecules in the 3 electronic levels B) The partition functions for the 3 electronic levels Qti, Qvib, Qrot, and the total partition function. C) The energies Eti, Evib, Etot, for the 3 electronic levels and the total energy and compare with the classical prediction. D) The fraction of molecules in the state J = 2, V = 2 of the second electronic level. Eye /cm-1 Ge wavelength/cm-1 Radius /10-10 0 2 1904.04 1.15077 43845.88 1 2374.31 1.0634 45793.78 2 1037.20 1.4167

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter18: More Statistical Thermodynamics
Section: Chapter Questions
Problem 18.4E
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he lowest electronic levels for 14N 160 have the following characteristics: Calculate, for 5000 k, using statistics. A) The fraction of molecules
in the 3 electronic levels B) The partition functions for the 3 electronic levels Qti, Qvib, Qrot, and the total partition function. C) The energies
Eti, Evib, Etot, for the 3 electronic levels and the total energy and compare with the classical prediction. D) The fraction of molecules in the
state J = 2, V = 2 of the second electronic level. Eye /cm-1 Ge wavelength/cm-1 Radius
/10-10 0 2 1904.04 1.15077 43845.88 1 2374.31 1.0634 45793.78 2 1037.20 1.4167
Transcribed Image Text:he lowest electronic levels for 14N 160 have the following characteristics: Calculate, for 5000 k, using statistics. A) The fraction of molecules in the 3 electronic levels B) The partition functions for the 3 electronic levels Qti, Qvib, Qrot, and the total partition function. C) The energies Eti, Evib, Etot, for the 3 electronic levels and the total energy and compare with the classical prediction. D) The fraction of molecules in the state J = 2, V = 2 of the second electronic level. Eye /cm-1 Ge wavelength/cm-1 Radius /10-10 0 2 1904.04 1.15077 43845.88 1 2374.31 1.0634 45793.78 2 1037.20 1.4167
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