For sucrose, C12H22011, [a]B = +66.5 deg. (a) Calculate the molecular rotation of sucrose. (b) Calculate the angle of rotation expected for a solution contain- ing sucrose at a concentration of g/L in a 10-cm cell. (c) A solution originally containing g hibits a = +18.6 deg in a 10-cm cell after a period of heating with acid (reaction on page 399). Calculate the fraction of su- crose which has been hydrolyzed. of sucrose per liter ex- 5g/L acid C12H22O11 + H2O C6H12O6 + C6H12O6 sucrose glucose fructose 1. [a° = +66.5° +52.7° -92.4° This reaction is termed an inversion because of the change in sign of the rotation that occurs. The concentration of sucrose is di- rectly proportional to the difference in rota- tion before and after inversion.

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B)Calculate the angle of rotation expected for a solution containing sucrose at a concentration of 5.00g/L in a 10cm cell.

ethods
13-12. For sucrose, C12H22O11, [a] = +66.5 deg.
(a) Calculate the molecular rotation of sucrose.
(b) Calculate the angle of rotation expected for a solution contain-
ing sucrose at a concentration of g/L in a 10-cm cell.
(c) A solution originally containing30 g of sucrose per liter ex-
hibits a = +18.6 deg in a 10-cm cell after a period of heating
with acid (reaction on page 399). Calculate the fraction of su-
crose which has been hydrolyzed.
5g/L
acid
C12H22O11 + H2O, C6H12O6 + C6H12O6
glucose
fructose
sucrose
[a = +66.5°
[a°
+52.7°
-92.4°
This reaction is termed an inversion because
of the change in sign of the rotation that
occurs. The concentration of sucrose is di-
rectly proportional to the difference in rota-
tion before and after inversion."
Transcribed Image Text:ethods 13-12. For sucrose, C12H22O11, [a] = +66.5 deg. (a) Calculate the molecular rotation of sucrose. (b) Calculate the angle of rotation expected for a solution contain- ing sucrose at a concentration of g/L in a 10-cm cell. (c) A solution originally containing30 g of sucrose per liter ex- hibits a = +18.6 deg in a 10-cm cell after a period of heating with acid (reaction on page 399). Calculate the fraction of su- crose which has been hydrolyzed. 5g/L acid C12H22O11 + H2O, C6H12O6 + C6H12O6 glucose fructose sucrose [a = +66.5° [a° +52.7° -92.4° This reaction is termed an inversion because of the change in sign of the rotation that occurs. The concentration of sucrose is di- rectly proportional to the difference in rota- tion before and after inversion."
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