Fluoride ion selective electrodes obey the following equation: E(V) = K - B(0.0592)log[F] where the fluoride concentration is expressed as mol/L and the temperature coefficient B is normally equal to 1. In a normal calibration procedure you dilute a standard fluoride solution to between 10 and 20 mg/L fluoride ion and then measure the response of the electrode. You then plot the data and do a linear regression to obtain the fitting coefficients K and B. Use the plotting and linear regression tools in Excel to calculate K and 3 from the data in the table. The coefficient 3 is close to 1, and can be determined from a calibration curve. F concentration (mg/L) 10.0 12.0 14.0 16.0 18.0 20.0 E(V) -0.395 -0.399 -0.403 -0.407 -0.410 -0.412 What value of K do you obtain from your plot? 4.0-0.586 |✓ What value of 3 do you obtain from your plot? 4.0 1.06 x

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
ChapterA1: Evaluation Of Analytical Data
Section: Chapter Questions
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Please help me with answering the second part. I have tried 1.06, 1.02, 0.98469, 0.985. Thank you for your help in advance1
Fluoride ion selective electrodes obey the following equation:
E(V) = K - B(0.0592)log[F]
where the fluoride concentration is expressed as mol/L and the temperature coefficient B is normally equal to 1.
In a normal calibration procedure you dilute a standard fluoride solution to between 10 and 20 mg/L fluoride ion and then measure the response of the electrode. You then plot the data and do a linear regression to obtain the fitting coefficients
K and B. Use the plotting and linear regression tools in Excel to calculate K and 3 from the data in the table. The coefficient 3 is close to 1, and can be determined from a calibration curve.
F concentration
(mg/L)
10.0
12.0
14.0
16.0
18.0
20.0
E(V)
-0.395
-0.399
-0.403
-0.407
-0.410
-0.412
What value of K do you obtain from your plot?
4.0-0.586
✓
What value of 3 do you obtain from your plot?
4.0 1.06
x
Transcribed Image Text:Fluoride ion selective electrodes obey the following equation: E(V) = K - B(0.0592)log[F] where the fluoride concentration is expressed as mol/L and the temperature coefficient B is normally equal to 1. In a normal calibration procedure you dilute a standard fluoride solution to between 10 and 20 mg/L fluoride ion and then measure the response of the electrode. You then plot the data and do a linear regression to obtain the fitting coefficients K and B. Use the plotting and linear regression tools in Excel to calculate K and 3 from the data in the table. The coefficient 3 is close to 1, and can be determined from a calibration curve. F concentration (mg/L) 10.0 12.0 14.0 16.0 18.0 20.0 E(V) -0.395 -0.399 -0.403 -0.407 -0.410 -0.412 What value of K do you obtain from your plot? 4.0-0.586 ✓ What value of 3 do you obtain from your plot? 4.0 1.06 x
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