Fill in the Blanks HCO,H(aq) H*(aq) + HCо, (aq) K 1.8 x 104 Blank 1 Blank 2 Blank 3 C Blank 4 Blank 5 Blank 6 Blank 7 Blank 8 Blank 9 Type your answers in all of the blanks and submit Consider the acid ionization reaction for formic acid that has a Ka =1.8x 10-4 HCO2H(aq) =H+ (aq) + HCO, (aq) Formic acid is a weak acid first found in ants. It causes the burning sensation when ants bite someone. Based upon a 0.15 M aqueous formic acid solution fill in the ICE table in the accompanying diagram then calculate the pH value for the solution. Only enter numerical values or algebraic quantities such +7x or -7x.

Fill in the Blanks HCO,H(aq) H*(aq) + HCо, (aq) K 1.8 x 104 Blank 1 Blank 2 Blank 3 C Blank 4 Blank 5 Blank 6 Blank 7 Blank 8 Blank 9 Type your answers in all of the blanks and submit Consider the acid ionization reaction for formic acid that has a Ka =1.8x 10-4 HCO2H(aq) =H+ (aq) + HCO, (aq) Formic acid is a weak acid first found in ants. It causes the burning sensation when ants bite someone. Based upon a 0.15 M aqueous formic acid solution fill in the ICE table in the accompanying diagram then calculate the pH value for the solution. Only enter numerical values or algebraic quantities such +7x or -7x.

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter13: Acids And Bases

Section: Chapter Questions

Problem 58QAP: Consider citric acid, H3C6H5O7, added to many soft drinks. The equilibrium constants for its...

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For each of the following reactions, predict whether the equilibrium lies predominantly to the left or to the right. Explain your predictions briefly. (a) NH4+(aq) + Br(aq) NH3(aq) + HBr(aq) (b) HPO42(aq) + CH3CO2(aq) PO43(aq) + CH3CO2H(aq) (c)[Fe(H2O)6]3+(aq) + HCO3(aq) [Fe(H2O)5(OH)]2+(aq) + H2CO3(aq)
Acrylic acid is used in the polymer industry in the production of acrylates. Its K, is 5.6 X 10“’. What is the pH of a 0.11 M solution of acrylic acid, CH2CHCOOH?
Consider citric acid, H3C6H5O7, added to many soft drinks. The equilibrium constants for its step-wise ionization areKa1=7.5104 ,Ka2=1.7105, andKa3=4.0107. Write the overall net ionic equation and calculate K for the complete ionization of citric acid.
Prove that Ka3 Kb1 = Kw for phosphoric acid, H3PO4, by adding the chemical equilibrium expressions that corresponds to the third ionization step of the acid in water with the first of the three successive steps of the reaction of phosphate ion, PO43, with water.
Determine Ka for hydrogen sulfate ion, HSO4-. In a 0.10-M solution the acid is 29% ionized.
Complete each of these reactions by filling in the blanks. Predict whether each reaction is product-favored or reactant-favored, and explain your reasoning. (a) _________ (aq) + Br(aq) NH3(aq) + HBr(aq) (b) CH3COOH(aq) + CN(aq) ________ (aq) + HCN(aq) (c) ________ (aq)+H2O () NH3(aq) + OH(aq)
The ionization constant of lactic acid, CH3CH(OH)CO2H, an acid found in the blood after strenuous exercise, is 1.36104. If 20.0 g of lactic acid is used to make a solution with a volume of 1.00 L, what is the concentration of hydronium ion in the solution?
What are the products of each of the following acid-base reactions? Indicate the acid and its conjugate base and the base and its conjugate acid. (a) HCIO4 + H2O (b) NH4 ++ H2O (c) HCO3 + OH
Kafor acetic acid (HC2H3O2) at 25°C is 1.754105 . At 50°C, Kais 1.633105 . Assuming that H° and S° are not affected by a change in temperature, calculate S° for the ionization of acetic acid.
Table 13-4 lists the stepwise Ka values for some polyprotic acids. What is the difference between a monoprotic acid, a diprotic acid, and a triprotic acid? Most polyprotic acids are weak acids; the major exception is H2SO4. To solve for the pH of a solution of H2SO4, you must generally solve a strong acid problem as well as a weak acid problem. Explain. Write out the reactions that refer to Ka1 and Ka2 for H2SO4. For H3PO4, Ka1 = 7.5 103, Ka2 = 6.2 108, and Ka3= 4.8 1013. Write out the reactions that refer to the Ka1, Ka2and Ka3equilibrium constants. What are the three acids in a solution of H3PO4? Which acid is strongest? What are the three conjugate bases in a solution of H3PO4? Which conjugate base is strongest? Summarize the strategy for calculating the pH of a polyprotic acid in water.
For conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)
A weak acid, HA, is a monoprotic acid. A solution that is 0.140 Min HA has a pH of 1.800 at 25°C. HA(aq) + H,0(1) 2 H;0"(aq) + A (aq) What is the acid-ionization constant, K, for this acid? What is the degree of ionization of the acid in this solution? Ka- Degree of ionization =