Exhibit 19-5 Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. H&C 45, H₂C XX H₂O
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- Exhibit 17-8 Name the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. CH3 CH3-C-CH₂-OH I CH3 H₂O* Use the editor to format your answerWhich of the following reactions will synthesize phenol from benzene? 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) warm H2SO4 and H2O 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) CuCN; 5) dilute acid and heat 1) Acetyl chloride & AlCl3; 2) bleach 1) Ph-N2+ + KI; 2) BrMgCH=CH2 in ether, followed by H3O+; 3) warm, conc'd KMnO4 1) Cl-CH(CH3)-CH2CH2CH3 + FeBr3; 2) hot, conc'd KMnO4Provide the structure(s) of the expected major organic product of the reaction shown. 1) Disiamylborane 2) H₂O₂, NaOH OI O II ||| O IV OV CH3CH₂C(CH3)2C=CH OH OH xx xo IV
- Please give the main substitution product for each of the following reactions, and indicate the dominant mechanism: (a) 1-bromopropane + NaOCH3 → (b) 3-bromo-3-methylpentane + NaOC2H5 →Provide the structure of the missing products or reactants. Show the relevant stereochemistry if necessary. H3C Br H₂O _SH [4© 1 product 2 products (2 isomers) ✓ OH + ?<What reagents are needed to synthesize the following bromides? Br Br Provide the major organic products obtained from the following reactions. a) SN1 CH;OH methanol b) DMF TsO Et CH;COONA SN2 Br, light
- Provide the structure of the product(s) with stereochemisty if appropriate. If multiple products indicate major product or if products are formed in equal amounts. If there is no reaction expected explain why. (a) OH HIO4 (the protecting group is remained) CHO H HOH2C OH (b) CHO -ОН NaCN # HO -H H -OH CH₂OH (c) CHO HO- -H HO -H NH₂OH 張一 H -OH H -OH CH₂OH i) Ba(OH)2 ii) MeOH, H₂SO4 NaOAc Ac₂0 NaOMe MeOHProvide the reagent(s) and the reaction mechanism of the following reaction H₂NChemical Reactions. Give the structure of the major organic products formed in each of the following reactions Br Br CH₂ONa CH₂OH t-BuOK DMSO +H₂N- 《》-NH,
- 27) Give the products of the reaction and provide a step-by-step mechanism for the formation of the products. O not + H₂O HCIPh3P-CHCH3 H₂C H3C Aldehydes and ketones are converted into alkenes by means of a direct nucleophilic addition called the Wittig reaction. In the reaction, a triphenylphosphorine ylide, also called a phosphorane, adds to an aldehyde/ketone to give a four-membered cyclic intermediate called an oxaphosphetane. The oxaphosphetane is not isolated but instead spontaneously decomposes to release triphenylphosphine oxide and an alkene. CH3 00 + The ylide is formed by reaction of triphenylphosphine, a good nucleophile, with a primary alkyl halide in an SN2 reaction, followed by deprotonation of the carbon with a strong base, such as butyllithium. The carbonyl carbon and the carbon originally bonded to the halogen become the two carbons with the double bond in the product alkene X m CH3 The real value of the Wittig reaction lies in its ability to yield an alkene of predictable structure, as the C=C bond is precisely where the C=O bond was in the reactant and no isomers (other than E/Z isomers)…Provide the mechanism for the following reaction (1) PhMgBr (2 equiv) (2) H3O+ workup OH