Consider the phase diagram of CO2 given below to answer the following questions: р 73,8 bar 5,2 bar 1,013 bar 194,7 K 216,6 K (-78,5 °C) (-56,6 °C) T 304,1 K (+31,0 °C) a) Fill in the blanks and label the respective phases (i.e. s, I, g and sc). b) Name the lines I, II and III in the diagram. What does it mean when a point lies on one of these lines? What happens when your system crosses the lines I, II, and III? c) Which phase transition(s) can CO2 undergo at a pressure of 1 atm? Give the approximate transition temperature(s). d) Name the two indicated points at (5.2 bar / 216.6 K) and (73.8 bar/304.1 K). What are the characteristics of these specific points? e) State Gibbs phase rule and determine the number of degrees of freedom for i) a point within one of the phases, ii) a point on one of the lines and iii) at the specific point at (5.2 bar / 216.6 K).
Consider the phase diagram of CO2 given below to answer the following questions: р 73,8 bar 5,2 bar 1,013 bar 194,7 K 216,6 K (-78,5 °C) (-56,6 °C) T 304,1 K (+31,0 °C) a) Fill in the blanks and label the respective phases (i.e. s, I, g and sc). b) Name the lines I, II and III in the diagram. What does it mean when a point lies on one of these lines? What happens when your system crosses the lines I, II, and III? c) Which phase transition(s) can CO2 undergo at a pressure of 1 atm? Give the approximate transition temperature(s). d) Name the two indicated points at (5.2 bar / 216.6 K) and (73.8 bar/304.1 K). What are the characteristics of these specific points? e) State Gibbs phase rule and determine the number of degrees of freedom for i) a point within one of the phases, ii) a point on one of the lines and iii) at the specific point at (5.2 bar / 216.6 K).
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter9: Liquids, Solids, And Materials
Section9.4: Solids And Changes Of Phase
Problem 9.9E
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