Consider the following reaction (DPPE structure below): F. - B(OH)2 F Ni(OTf)2 DPPE K2CO3 (a) Give the product of the reaction and suggest a plausible catalytic cycle giving the number of d-electrons and the oxidation state of Ni in each intermediate.

Consider the following reaction (DPPE structure below): F. - B(OH)2 F Ni(OTf)2 DPPE K2CO3 (a) Give the product of the reaction and suggest a plausible catalytic cycle giving the number of d-electrons and the oxidation state of Ni in each intermediate.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter5: Stereochemistry At Tetrahedral Centers

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Question

Consider the following reaction (DPPE structure below):
F.
B(OH)2
F
Ni(OTf)2
+
DPPE
K2CO3
(а)
Give the product of the reaction and suggest a plausible catalytic cycle giving
the number of d-electrons and the oxidation state of Ni in each intermediate.

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