(b) Complete the following reactions by filling in the missing reactants, products orreagents (E-N).OHE(i)CH-CH-CH3CH-Č-CH3H*H,O/H*НCN(ii) CH-C-CH3GHeatNABH4(iii) CH-C-CH3H*The UniversiymesterCH;CH,MgBrCH,OH(iv)JK%3DH*H*L.(v) CH-CH,-CH,OHCH;CH,COOHCH;CH,-Ĉ--CICH,NH,(vi) CH3CH,-Č

Answered: Image /qna-images/answer/0cf624b1-cc1b-41f4-a172-ad8f7aaf84d6.jpg

Complete the following reactions by filling in the missing reactants, products or reagents (E-N). ... ... OH E CH3MgBr (i) CH;-CH-CH, CH--CH, F H* HCN H,0/H* (ii) CH-C-CH3 G Heat NABH4 I! (iii) CH-C-CH3 H*

Complete the following reactions by filling in the missing reactants, products or reagents (E-N). ... ... OH E CH3MgBr (i) CH;-CH-CH, CH--CH, F H* HCN H,0/H* (ii) CH-C-CH3 G Heat NABH4 I! (iii) CH-C-CH3 H*

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 64AP: The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold...

See similar textbooks

Related questions

Q: ind ΔH for the reaction C3H8 (l) + 5O2(g) --> 3CO2(g) + 4H2O(l) ΔHrxn = ? Given:…

A: for the reaction C3H8 (l) + 5O2(g) --> 3CO2(g) + 4H2O(l) ΔHrxn = ? Given: [CO2(g)] =…

Q: Calculate the AHo f of C6H1206(s) from the following data: AH combustion of C6H1206(s) = -2816kJ/mol…

Q: Use the table of Bond Energies (BE) in the table below to calculate the Heat of Reaction, AHxg for…

A: Given:

Q: Draw the orgamic molecule(s) which is(are) formed in the following reaction. Do not include…

Q: AH solution= qreaction /n salt Lab 18 Part 1: Determination of calorimeter constant AH (glucose) AH…

A: The ∆Hrxn is calculated by the formula, ∆Hrxn=∑nHfproducts-∑mHfreactants The Qcomb is calculated by…

Q: For generic reaction, determine the value of ∆H2 in terms of ∆H1.A + 1/2 B -------> C ∆H12 A +…

A: The Heat of Reaction (also known and Enthalpy of Reaction) is the change in the enthalpy of a…

Q: a) When 2.76 g of potassium carbonate was added to 30.0 cm3 of approximately 2 mol dm hydrochloric…

A: Since you have posted a question with multiple sub-parts, we will solve first three subparts for…

Q: A pellet of benzoic acid standard was combusted in a bomb calorimeter to determine the experimental…

Q: Carbon dioxide from the atmosphere "weathers," or dissolves, limestone (CaCO3) by the reaction…

A: Given: We have to calculate the enthalpy change for the reaction.

Q: pellet of benzoic acid standard was combusted in a bomb calorimeter to determine the experimental…

Q: Hydrogen reacts with nitrogen to form ammonia (NH3) according to the reaction N2(g) + 3H2(g) =…

A: Given, ∆H ° = -173 kj/mol ∆S° = - 196 J/mol.K Temperature = 25°C ∆G° = ?

Q: We can calculate ΔH for the reaction C(s)+ H2O(g)= CO(g)+H2(g) using the following thermohemical…

A: According to the Hess's law, on multiplying the reaction with a constant, the value of its ΔH also…

Q: Given the following heats of reaction: H2(g) + 1/2 O2(g) ---> H2O(g) ΔH = - 241.8…

Q: For the reaction : N,Ham + Oz@) – Nze) + 2H2Om AH = -622.4 kJ The quantity of heat produced by the…

A: In the given reaction the hydrazine reacts with oxygen to form nitrogen and water. The equation for…

Q: Q4. Another way to calculate AH values that cannot be measured experimentally is with standard heats…

A: Given;

Q: The following table is the data a student recorded after completing the Hess' Law Lab (VCL 3-12).…

A: Answer is explained below.

Q: Given the following heats of formation below the AH for the reaction is kJ 3NO2(g) + H2O(1) -->…

A: The reaction given is

Q: a) Balance the following reaction. What are the values of a, b, x, and y a C3H6 (g) + b 02 ) →x C02…

Q: 70. Given the following data → Cl,0(g) + F;O(g) - 2CIF(g) + O;(g) AH = 167.4 kJ ΔΗ %3D 2CIF;(g) +…

A: The reactions given are 1) 2 ClF (g) + O2 (g) -------> Cl2O (g) + F2O (g)…

Q: Calculate ASuniy for the following reaction at 25 °C: 2C2H6(g) + 7 O2(g) 2 4CO2(g) + 6 H20({) ΔΗ…

Q: Nitric acid, HNO3, was first prepared 1200 years ago by heating naturally occurring sodium nitrate…

Q: Which of the following is TRUE for the combustion of liquid octane (C3H18) in the presence of excess…

A: Standard enthalpy of combustion is defined as the enthalpy change when one mole of a compound is…

Q: Syngas can be burned directly or converted to methanol. Calculate AH° for the reaction CO(g) + 2H2…

A: The species methanol will be generated from the species carbon monoxide and the species hydrogen…

Q: 21. CH3CH=CH2 – CH3CH2CH3 What reactants (and catalysts) are needed to make the reaction above…

Q: Determine AH for the following reaction: C2H2(g) + 2 H2(g) → C2H6(g); AH =? given the following…

A: 8. Given reaction, C2H2(g) + 2 H2(g) → C2H6(g) ∆H = ?

Q: The density of all solutions are 1.0g/mL and their respective heat capacities 4.184J/g.K.…

A: The heat of reaction qr can be calculated by this general formula Q = mC (change in temperature)…

Q: Given the data below, H°, for the reaction rxn 2SO2 (g) + O2 (g) → 2SO3 (g) is kJ. AH°; (SO2 (g)) =…

A: O2(g) is pure gas at room temperature so it's ∆H°formation is Zero. So we not need value of O2

Q: 1. Calculate ∆G° for the combustion of ethane 2C2H6(g) + 7O2(g) → 4CO2(g) + 6H2O(l) With the…

A: The ∆Grxn0 is given by the ∆Gproducts and ∆Greactants.

Q: Consider the following balanced chemical equation for the combustion of pentane (C5H12): C5H12() + 8…

A: The reactions given are, 1) 5 C (s) + 6 H2 (g) ------> C5H12 (l) ΔH =…

Q: Q4. Another way to calculate AH values that cannot be measured experimentally is with standard heats…

A: Given, Enthalpy of hydration (∆Hreaction) for anhydrous sodium acetate = - 495.71 KJ / mol ( Using…

Q: Find AGpen for the reaction: 3 C(s) + 4 Hk(g) CaHs(g) Use the following reactions with known values…

A: The value of ∆G depends on the Stoichiometry of the chemical equation If a chemical equation is…

Q: Mass of Cheeto (before heating).... _1.670g_ Mass of Cheeto (after heating)... 190g Mass of Cheeto…

A: Given : Mass of water = 100.0 g And change in temperature of water = 20.7 oC

Q: Stearic acid (C18H3602) is a fatty acid, a molecule with a long hydrocarbon chain and an organic…

A: Combustion Reaction: These are the reactions in which hydrocarbon reacts in the presence of oxygen…

Q: Given the data in the table below and AH°rxn for the reaction SO2C12 (g) + 2H2O (1) → H2SO4 (1) +…

Q: Which value (if any) corresponds to a faster reaction: (a) Ea = 40 kJ/mol or Ea = 4 kJ/mol; (b) a…

A: (a)The activation energy generally denotes the amount of energy required to complete the reaction.…

Q: The heat of combustion of liquid octane (C3H130) to carbon dioxide in liquid water at 298 K is…

Q: What is ∆G° for the reaction CH₃OH(g) → CO(g) + 2 H₂(g) at 25°C?

A: Given reaction at 25°C: CH₃OH(g) → CO(g) + 2H₂(g) ∆G° value of CH₃OH(g) = -162.42 KJ/mol ∆G° value…

Q: Calculate ΔHrxn for the reaction: 7 C (s) + 8 H2 (g) → C7H16 (g) The following reactions and…

A: Given steps reactions are : Reaction A: C7H16 (g) + 11O2 (g) → 7CO2 (g) + 8H2O (g), ΔH1 = - 4817 kJ…

Q: Green plants utilize sunlight to convert CO2 and H2O to glucose (C6H1206) and 02. Use the…

A: The question is based on the concept of chemical thermodynamics. We have to calculate the enthalpy…

Q: Calculate AHrxn for the following reaction: C(s) +H20(g)→CO(g) +H2 (g) Use the following reactions…

Q: Ah when 0.75215 of ben z0ic was burred in a calorimeta Containins ,0o0 of water termperaAure rise of…

A: mass of benzoic acid = 0.7521 g mass of water = 1000 g change in temperature = 3.60 degree C heat…

Q: What is the value of AG (kJ mol-1) for this reaction at 320.1 °C? The data refer to 25 °C: 2 PC13…

Q: For the reaction: Al,O;(s) + AICI;(s) + 3NO(g) + 6H20(g) 3Al(s) + 3 NH,CI0,(s) Calculate AH° for the…

A: The delta H0 of the reaction is to be calculated.

Q: Calculate AHrxn for the reaction: 7 (s) + 8 H2 (g) → C;H16 (g) The following reactions and…

Q: 41. Pentaborane-9, BsH9, is a colorless, highly reactive liquid that will burst into flame or even…

A: Given, 2B5H9(l) + 12 O2(g) → 5 B2O3(s) + 9 H2O(l) The standard enthalpy of a reaction is:

Q: What is the value of AG (kJ mol-1) for this reaction at 57.4 °C? The data refer to 25 °C: P2 (g) +…

Q: kindly answer all questions correctly with detailed explanation step by step for upvotes otherwise 5…

A: Given: Initial temperature = 25oC Final temperature = 720C Equilibrium moles of Br2 = 0.7 moles…

Q: Which of the following is TRUE for the combustion of liquid octane (C8H18) in the presence of excess…

Q: Given the data in the table below, AH, for the reaction rxn IF5 (g) + F2 (g) → IF7 (g) AHᵒf…

A: The standard enthalpy of formation is the enthalpy change of reaction in standard conditions when…

Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

(b) Complete the following reactions by filling in the missing reactants, products or
reagents (E-N).
OH
E
(i)
CH-CH-CH3
CH-Č-CH3
H*
H,O/H*
НCN
(ii) CH-C
-CH3
G
Heat
NABH4
(iii) CH-C-CH3
H*
The Universiy
mester
CH;CH,MgBr
CH,OH
(iv)
J
K
%3D
H*
H*
L.
(v) CH-CH,-CH,OH
CH;CH,COOH
CH;CH,-Ĉ--CI
CH,NH,
(vi) CH3CH,-Č

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

The reagent has to be given.

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Draw the structure of the products formed in the following reactions. a) CN H,0, H* CH3 он b) H3C- -CI + CH3 c) CH3 KMNO4, A, H,O" CH3 d) Br Mg, éther CO, H*
Formulate the products from the following reactions. PHNH,, CH3COOH Meo OMe heat EtO2C CH2 CO2ET i) CH;COOH H3C H2N CH3 ii) [0]
What starting materials are needed to synthesize each azo compounds O2N H2N- -N=N- CI но -N=N- -CH3 I0 Fill in the reagent or starting material needed or product in each reaction a) CgH;CH;CH;CH2Br CGH;CH;CH;CH¿NH2 b) C,H;CH;CH;CH2CONH, CH,CH;CH;CH;NH2 HCI P-CH;C,H4NH2 NANO2 P-CH;C,H&NH2 HCI/H;0 P-CH3C,H4NH2 CH;COCI
(c) Complete the following reactions : HNO3/(CH3CO)20 A + B Major Minor OʻBu (ü) Ph-N=N C NaOH -N- Br2/CH3COOH D (üi) -NH2
Provide the structure of the product(s) with stereochemisty if appropriate. If multiple products indicate major product or if products are formed in equal amounts. If there is no reaction expected explain why. (a) OH HIO4 (the protecting group is remained) CHO H HOH2C OH (b) CHO -ОН NaCN # HO -H H -OH CH₂OH (c) CHO HO- -H HO -H NH₂OH 張一 H -OH H -OH CH₂OH i) Ba(OH)2 ii) MeOH, H₂SO4 NaOAc Ac₂0 NaOMe MeOH
What is/are the missing reagent(s) (A) in the following reaction? CH3-CH₂-C-OH O H₂SO4 O CH3OCH 3 O 1)CN 2) H3O+/heat O CrO3/H+ OCH3OH/H*/heat A CH3-CH₂-C-0-CH3
What is the expected product of this reaction scquence? NaC CCH CHCH Br Na THE hgNH (А) CH,CH,CH,с — сн CH,CH, (D) (B) (с сн, сH,сH, Cн СH, CH CH,CH CH,
#2 - Draw the step-by-step mechanism for each of the steps in the following reaction sequence. Be sure to draw arrows for the movement of all electrons. Show any and all intermediates. ОН CH–C=C-CH2CH3 (1) Na* -:C=C-CH;CH3 NaNH, H-C=C-CH;CH3 (2) H;O+
What is/are the expected major product(s) of the following reaction? (A) (B) (C) لد OHON OH (0) Ho HO OH + NaBH4 EtOH OH OH O OH O 왜? 왜? ? Rectangular Snip
OH - NH, Br2/KOH →product; 1. (a-hydroxy amide) Product of this Hoffmann bromamide reaction is : OH (a) Ph – Ĉ-CH3 (Ъ) Ph — CHO (c) Ph- CH3 (d) Ph – CH2 -NH2 NO2
What is the major product of the reaction below? 1) NaOMe 2) H₂O OH (A) OMe НО, (B) OMe MeO. (C) ? OH MeO (D) OH
What reagents are required for the below conversion: OH (A) (CH2=CH),CuLi ; H,O, HCl (В) CН-CH-СuLi (C) MGB ; H20, HC1 (D) MgBr, ether ; CH2-CH2 , H2O