CnH14O (triplet) 10 8 6 PPM 2 (doubet) 2 (triplet) 2 (sixtet) 2 3 (triplet) 0

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter8: An Introduction To Optical Atomic Spectrometry
Section: Chapter Questions
Problem 8.3QAP
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(31) Which of the following structures corresponds to the attached 1H-NMR spectrum?

CH14O
1
(triplet)
10
-CH₂
-CH₂-
-CH-
-G-G-CH₂
-&-CH₂
PPM
TABLE 13.1 Approximate Values of Chemical Shifts for ¹H NMR
Type of proton
(CH)),Si
-CH₂
-C-C-H
R-O-CH₂
R-C-CH₂
8
R-C-C-H
0.9
1.3
Approximate chemical shift (ppm) Type of proton
1.4
1.7
2.1
2.3
2.4
6
4.7
5.3
&H
|--#
Br-c-H
C-C-H
RNH₂
2
(doubet)
ROH
ArOH
Lon
"The values are approximate because they are affected by neighboring substituents.
2
(triplet)
9.0-10
2.5-4
Approximate chemical shift (ppm)
6.5-8
2.5-4
I
445
variable, 1.5-4
variable, 2-5
variable, 4-7
2
(sixtet)
variable, 10-12
2
3
(triplet)
Transcribed Image Text:CH14O 1 (triplet) 10 -CH₂ -CH₂- -CH- -G-G-CH₂ -&-CH₂ PPM TABLE 13.1 Approximate Values of Chemical Shifts for ¹H NMR Type of proton (CH)),Si -CH₂ -C-C-H R-O-CH₂ R-C-CH₂ 8 R-C-C-H 0.9 1.3 Approximate chemical shift (ppm) Type of proton 1.4 1.7 2.1 2.3 2.4 6 4.7 5.3 &H |--# Br-c-H C-C-H RNH₂ 2 (doubet) ROH ArOH Lon "The values are approximate because they are affected by neighboring substituents. 2 (triplet) 9.0-10 2.5-4 Approximate chemical shift (ppm) 6.5-8 2.5-4 I 445 variable, 1.5-4 variable, 2-5 variable, 4-7 2 (sixtet) variable, 10-12 2 3 (triplet)
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