Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. 2. d 3. a CH3 -Se: Inductive effect a CH3 :0: || O-CCH₂CH₂CCH3 :0: :0: || -CH=CH-C-ÖCH3 . Resonance effect d Inductive effect a Inductive effect a Resonance effect Resonance effect

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Chapter1: Chemical Foundations
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Classify the following substituents according to whether they are electron donors or
electron acceptors relative to hydrogen by the resonance and the inductive
mechanisms.
a = acceptor
d = donor
n = no effect
1.
2.
d
3.
a
CH3
-Se:
CH3
Inductive effect a
:0:
-O-CCH₂CH₂CCH3
CCH₂CH
:0:
:0:
||
-CH=CH-C-OCH3
Resonance effect d
Inductive effect a
Inductive effect a
.
Resonance effect
Resonance effect
Transcribed Image Text:Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. 2. d 3. a CH3 -Se: CH3 Inductive effect a :0: -O-CCH₂CH₂CCH3 CCH₂CH :0: :0: || -CH=CH-C-OCH3 Resonance effect d Inductive effect a Inductive effect a . Resonance effect Resonance effect
Y+
000 X
+
Electrophilic aromatic substitution is a two-step process. In the first st
an electrophile, here generically shown as Y+, reacts with the aromati
ring to form a resonance-stabilized carbocation intermediate. In the
second step, loss of a proton from the site of attack restores aromatic
to the ring and completes the reaction.
Draw curved arrows to show the movement of electrons in this step of
mechanism.
Arrow-pushing Instructions
+
H*
H
Transcribed Image Text:Y+ 000 X + Electrophilic aromatic substitution is a two-step process. In the first st an electrophile, here generically shown as Y+, reacts with the aromati ring to form a resonance-stabilized carbocation intermediate. In the second step, loss of a proton from the site of attack restores aromatic to the ring and completes the reaction. Draw curved arrows to show the movement of electrons in this step of mechanism. Arrow-pushing Instructions + H* H
Expert Solution
Step 1

Se (Selenium) is an element in group 16 (oxygen family). A positive charge on Se decreases the electron density on it , thereby increasing the electron-withdrawing nature of the group.

This means its resonance effect will be acceptor.

Resonenece effect    a

All other answers are correct

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