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- Q 1. At 291 K, the equivalent conductivities at infinite dilution of HCI NaCl and CH3COONA are 369.3, 101.7 and 1.7 S cm2eq-1 respectively. If equivalent conductivity of centinormal solution of acetic acid is 14.3 S cmzeq 1, [H+] in solution of acetic acid is Xx10 . Calculate of Value of X?Q 1. At 291 K, the equivalent conductivities at infinite dilution of HCl „NaCl and CH3COONA are 369.3, 101.7 and 1.7 S cm2eq-1 respectively. If equivalent conductivity of centinormal solution of acetic acid is 14.3 S cm2eq-1, [H+]in solution of acetic acid is Xx104. Calculate of Value of X?Q: The concentration of the sulphate ion in a mineral water can be determinedby the turbidity which results from the addition of excess BaCl2, to a quantityof measured sample. A turbidometer used for this analysis has been standardisedwith a series of standard solutions of NaSO4. The following resultswere obtained:Standard solution Conc. (SO4)2− (mg/L) Reading of turbidometerS0 0.00 0.06S1 5.00 1.48S2 10.00 2.28S3 15.00 3.98S4 20.00 4.61i. In supposing that a linear relationship exists between the readings takenfrom the apparatus and the sulphur ion concentration, derive an equationrelating readings of the turbidometer and sulphate concentration(method of least squares).ii. Calculate the concentration of sulphate in a sample of mineral waterfor which the turbidometer gives a reading of 3.67.
- Calculate the values expected for the total alkalinity and for the phenol- phthalein alkalinity of a 25°C saturated solution of calcium carbonate in water, and compare them to the values for a solution that also is in equilib- rium with atmospheric carbon dioxide. Use the concentrations quoted in the last column of Table 10-4.A reaction mixture (mixture 1) at 298 K has a N2O4(g) partial pressure of 0.1 bar anda NO2(g) partial pressure of 0.05 bar. Calculate the reaction Gibbs energy (∆??) formixture 1 at 298 K. A second reaction mixture (mixture 2) is prepared at 298 K with a N2O4(g) partialpressure of 0.05 bar and a NO2(g) partial pressure of 0.10 bar. (i) Calculate the reaction Gibbs energy (∆??) for mixture 2 at 298 K. (ii) Comment on the spontaneity of the forward reaction for mixture 1 and mixture 2.Support your answer with the values of ∆?? calculated for the two mixtures. please give solution and answer9. The molar conductivity values at infinite dilution, in units of Sm?mol1, of NHẠCI, NaCl and N2OH are 1.497 x 10², 1.2645 x 10² and 2.478 x 10², respectively. (a) Calculate the molar conductivity at infinite dilution of NH4OH. (b) The molar conductivity of 0.0100 moldm3 NH,OH is 1.13 x 103 Sm?mol. What is the degree of dissociation and the dissociation constant, Kp, of 0.0100 moldm3 NHẠOH?
- Q2 At 291 K, the equivalent conductivities at infinite dilution of HCI, NaCl and CH3COONA are 369.3, 101.7 and 71.7 S cm2 eq-1 respectively. If equivalent conductivity of centinormal solution of acetic acid is 14.3 S cm2 eq-1, Calculate of the degree of dissociation (in %) of CH3COOH ?The mean activity coefficient in an 0.050 molKg-1 LaCl3 (aq) solutions is 0.303 at 25 o C. What is the percentage error in the value predicted by the debye – Huckel limiting law?Q1. Dissolved 0.273 grams of pure sodium oxalate (Na,C,O.) in distilled water and added sulfuric acid and titration the solution at 70 ° C by using 42.68 ml of KMNO, solution and has exceeded end point limits by using 1.46 ml of standard oxalic acid (H; C;O.) with 0.1024 N. Calculate the normlity of KMN0.. Note that the molecular weight of sodium oxalate (Na,C,O.) = 134 and its equivalent weight = 67
- Determine the activity coefficients and effective concentrations (activities) of Na+ and Ca2+ ions in an aqueous solution having the following composition: [Ca2+] = 3.25x 10-3 M; [Na+] = 0.96x 10-3 M; [HCO3-] = 5.75x 10-3 M; [SO42-] = 0.89x 10-3 M. (Note: Solvated ionic radii are: a(HCO3-) = a(SO42-) = 4 Å; a(Ca+) = 6 Å)A reaction mixture (mixture 1) at 298 K has a N2O4(g) partial pressure of 0.1 bar anda NO2(g) partial pressure of 0.05 bar. Calculate the reaction Gibbs energy (∆??) formixture 1 at 298 K. please give solution and answerQ1. Dissolved 0.273 grams of pure sodium oxalate (Na.C,O.) in distilled water and added sulfuric acid and titration the solution at 70 ° C by using 42.68 ml of KMNO, solution and has exceeded end point limits by using 1.46 ml of standard oxalic acid (H; C.O.) with 0.1024 N. Calculate the normlity of KMNO. Note that the molecular weight of sodium oxalate (Na,C,O.) = 134 and its equivalent weight = 67