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Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g)→ CO,(g) + NO(g) is suggested to be (1) 2 NO,(g) (3)ON + (3)ON NO, (g) + CO,(g) k2 (2) NO, (g) + CO(g) · 3) NO219) +Coa)7 NOg) +cOzeg) The experimental rate law for the production of [CO2] = k1 [NO2]? or d[CO2] . k[NO2]? %3D dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[NO3] , d[Co2] = ? ) dt = ? and that [NO3] and [CO2] are created and destroyed, dt

Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g)→ CO,(g) + NO(g) is suggested to be (1) 2 NO,(g) (3)ON + (3)ON NO, (g) + CO,(g) k2 (2) NO, (g) + CO(g) · 3) NO219) +Coa)7 NOg) +cOzeg) The experimental rate law for the production of [CO2] = k1 [NO2]? or d[CO2] . k[NO2]? %3D dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[NO3] , d[Co2] = ? ) dt = ? and that [NO3] and [CO2] are created and destroyed, dt

Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 65GQ: The thermal decomposition of diacetylene, C4H2, was studied at 950 C. Use the following data (K. C....
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Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g) - → CO,(g) + NO(g) is suggested to be (1) 2 NO,(g) –→ NO,(g) + NO(g) k2 (2) NO,(g) + CO(g) - NO, (g) + CO,g) 3) NO219) +Coca) > NOg) + cOz eg) The experimental rate law for the production of [CO2] = ki [NO2]? or d[CO2] k [NO2]? dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[CO2] that [NO3] and [CO2] are created and destroyed, INO3] = ? dt and = ? ) dt
Transcribed Image Text:Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g) - → CO,(g) + NO(g) is suggested to be (1) 2 NO,(g) –→ NO,(g) + NO(g) k2 (2) NO,(g) + CO(g) - NO, (g) + CO,g) 3) NO219) +Coca) > NOg) + cOz eg) The experimental rate law for the production of [CO2] = ki [NO2]? or d[CO2] k [NO2]? dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[CO2] that [NO3] and [CO2] are created and destroyed, INO3] = ? dt and = ? ) dt
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