Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g) → CO,) + NO(g) is suggested to be k (1) 2 NO,(g) NO,(g) + NO(g) (2) NO,g) + CO(g) → NO,(g) + Co,(g) 3) NO219) +COca)7 NOg) + COz eg) The experimental rate law for the production of [CO2] = k, [NO2J or d[CO2) k,[NO2]2 %3D dt = 0 ), is this a valid mechanism? i.e show dt d[NO3] Assuming that [NO3] is governed by a steady state (* that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[NO3] a[CO2=?) that [NO3] and [CO2] are created and destroyed, : ? and %3D dt dt following elec cal cll 25C

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Chapter11: Chemical Kinetics
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Chemical Mechanism
8.
The mechanism for the reaction described by
NO,(g) + CO(g)→ CO,(g) + NO(g)
anhe d
is suggested to be
(1) 2 NO,(g)
NO, (g) + NO(g)
(2) NO,(g) + CO(g) NO,(g) + Co,(g)
3) NO219) +Coca) > NOg) +c0ze9)
The experimental rate law for the production of [CO2] = k, [NO2J² or
d[CO2]
ka[NO2]?
%3D
dt
d[NO3]
Assuming that [NO3] is governed by a steady state (
= 0 ), is this a valid mechanism? i.e show
dt
that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways
that [NO3] and [CO2] are created and destroyed,
d[NO3]
= ?
dt
d[CO2]
= ? )
dt
and
25C
Transcribed Image Text:Chemical Mechanism 8. The mechanism for the reaction described by NO,(g) + CO(g)→ CO,(g) + NO(g) anhe d is suggested to be (1) 2 NO,(g) NO, (g) + NO(g) (2) NO,(g) + CO(g) NO,(g) + Co,(g) 3) NO219) +Coca) > NOg) +c0ze9) The experimental rate law for the production of [CO2] = k, [NO2J² or d[CO2] ka[NO2]? %3D dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways that [NO3] and [CO2] are created and destroyed, d[NO3] = ? dt d[CO2] = ? ) dt and 25C
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