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The cyclobutenyl dichloride below reacts with the powerful Lewis acid antimony pentafluoride in liquid SO2 at -75o to give a pale yellow solution that exhibits one singlet at 3.68 ppm in its 1H-NMR spectrum. The species in solution has been deduced to be the salt C8H12X2 where X is an hexahaloantimonate anion.
Draw the cation part of the salt C8H12X2
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- Give balanced equabion for the reachon la CH3- CO,H t CH3-CHOH CO2 HWhat s 9somer? wrfte an down the isomers of the Compound whase formula is CHq Cl. It Psomers have a chiral which of the can structure. E xamine Pt terms of stereochemistry.НО 0 OH + CV (NO3)3 911₂0 → HH₂0, 120 °C₂0 4 24h 0 Used 0.839) - Brephthalic and Used 2,0g - (r(NO3)3 "9H₂0) lonik
- 131 bas (AL [3) hms (8)-01 12. Complete the skeleton below to show the following structure: (1S,2S,5R)-5-methoxy-2-methylcyclohexanamine.+ OCH3 DMSO Br H Br + CH;OH "CH¿CH2CH3Consider the following equilibrium: O || R-C-H + HCN HO OH R-C-H | CN (A) When R = CH3CH2-, Keq = 1. (i) Predict whether Keq should be greater or less than 1 when R = CICH2, and (ii) when R is CH2=CH. Explain. (B) In the case where R is CH2=CH, the cyanohydrin is formed faster but given enough time, another constitutional isomeric C4H5NO product predominates. Explain and write a base-catalyzed mechanism for the formation of the other isomer. Recall that: HO HON N
- Identify the relationship between the following compounds. H3C COOH ; HOOC CH ОН enantiomers diastereomers H™ HI!.. HO O achiral O No answer text provided. CH3TLNEVE-++ACOD n t t G 80. n Tuu 30 BRE 40 20 Oc C d 4000 a b 3600 (a) CH-CH₂-CH₂-CH₂-C=CH (B) CH-CH2-CH2-CH2-CH2-CI (c) CH-CH₂-CH₂-CH₂-CH-CH₂ (d) CH,CH2-CH2-CH2-CH2-CH3 2000 2600 Wa venumberc 2000 1600 1000 600+ NH₂ HO Ja'qub ||| Tamsulosin is a pharmaceutical used to treat an enlarged prostate. Choose the compound that would be suitable for preparing the necessary diastereomeric salts to purify the racemic mixture of tamsulosin shown below. OH IV НО. O OH OH NH₂ OH OH A) I B) II D) IV