Calculate the isotope shift in the fundamental vibrational frequencies of 2H9Br H with respect to 1H79 If the value of force constant is 380 cm for all the three isotopes. 0 cm, -620 cm¹ 0 cm, -731 cm¹ o-2 cm, -816 cm¹ -2 cm, -750 cm -1

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter18: More Statistical Thermodynamics
Section: Chapter Questions
Problem 18.25E
Question
Calculate the Isotope shift in the fundamental vibrational frequencies of
HBr 'H"
-1
0 cm, -620 cm"
0 cm³¹, -731 cm¹
-2 cm, -816 cm¹
-2 cm, -750 cm¹
1H79
with respect to
If the value of force constant is
380 cm
-1
for all the three Isotopes.
Transcribed Image Text:Calculate the Isotope shift in the fundamental vibrational frequencies of HBr 'H" -1 0 cm, -620 cm" 0 cm³¹, -731 cm¹ -2 cm, -816 cm¹ -2 cm, -750 cm¹ 1H79 with respect to If the value of force constant is 380 cm -1 for all the three Isotopes.
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