c) H₂C₁ 11 Quartet Integration=1 This signal is actually a pair of doublets (with a total integration-4) b. For the NMR spectrum, draw the structure of the product for part a) next to the spectrum and label the protons so that they match the letter labels shown on the NMR spectrum. Fill in the Chemical shift, integration and multiplicity in the table. (Treat E and F as separate signals). 10 HOP-01-062 Br STRUCTURE: E and F 1. Mg/diethyl ether 2. O 7 Doublet Integration - 3 "H 3. H*/H₂O Singlet Integration - 3 6 Singlet Integration Proton label ppm A B C D E F 5 4 Chemical shift (ppm) For the reaction product for part 1.c) above, the IR and NMR spectra are shown below". a. For the IR spectrum, identify which functional groups are suggested by the signals indicated by each of the arrows. Relative integration Multiplicity c. Explain the multiplicity and relative integration for the peak labelled HA. d. Explain the multiplicity and relative integration for the peak labelled HD. e. The product of the reaction shown in a) could be synthesized using a different combination of Grignard reagent and carbonyl compound. Write the reaction to sho this reaction.

Macroscale and Microscale Organic Experiments
7th Edition
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Kenneth L. Williamson, Katherine M. Masters
Chapter65: Biosynthesis Of Ethanol And Enzymatic Reactions
Section: Chapter Questions
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Please answer this question pertaining to organic chemistry.
C)
H₂C
11
Quartet
Integration=1
This signalis
actually a pair of
doublets (with a
total integration - 4)
10
b. For the NMR spectrum, draw the structure of the product for part a) next to the spectrum
and label the protons so that they match the letter labels shown on the NMR spectrum.
Fill in the Chemical shift, integration and multiplicity in the table. (Treat E and F as
separate signals).
HSP-01-062
STRUCTURE:
9
Br
E and F
8
1. Mg/diethyl ether
2.
O
²i
H
3. H*/H₂O
7
Doublet
Integration - 3
Singlet
Integration - 3
6
Proton
label
A
B
с
ppm
D
E
LL
Singlet
Integration-1
F
D
Chemical
shift (ppm)
3
2.
B
2
Relative
integration
For the reaction product for part 1.c) above, the IR and NMR spectra are shown below*
a. For the IR spectrum, identify which functional groups are suggested by the signals
indicated by each of the arrows.
Multiplicity
0
Vi
c. Explain the multiplicity and relative integration for the peak labelled H A.
d. Explain the multiplicity and relative integration for the peak labelled HD.
e. The product of the reaction shown in a) could be synthesized using a different
combination of Grignard reagent and carbonyl compound. Write the reaction to show
this reaction.
Transcribed Image Text:C) H₂C 11 Quartet Integration=1 This signalis actually a pair of doublets (with a total integration - 4) 10 b. For the NMR spectrum, draw the structure of the product for part a) next to the spectrum and label the protons so that they match the letter labels shown on the NMR spectrum. Fill in the Chemical shift, integration and multiplicity in the table. (Treat E and F as separate signals). HSP-01-062 STRUCTURE: 9 Br E and F 8 1. Mg/diethyl ether 2. O ²i H 3. H*/H₂O 7 Doublet Integration - 3 Singlet Integration - 3 6 Proton label A B с ppm D E LL Singlet Integration-1 F D Chemical shift (ppm) 3 2. B 2 Relative integration For the reaction product for part 1.c) above, the IR and NMR spectra are shown below* a. For the IR spectrum, identify which functional groups are suggested by the signals indicated by each of the arrows. Multiplicity 0 Vi c. Explain the multiplicity and relative integration for the peak labelled H A. d. Explain the multiplicity and relative integration for the peak labelled HD. e. The product of the reaction shown in a) could be synthesized using a different combination of Grignard reagent and carbonyl compound. Write the reaction to show this reaction.
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