Butadiene, C4H6, is a planar molecule that has the followingcarbon–carbon bond lengths:(a) Predict the bond angles around each of the carbon atomsand sketch the molecule. (b) From left to right, whatis the hybridization of each carbon atom in butadiene?(c) The middle C¬C bond length in butadiene (1.48 Å) isa little shorter than the average C¬C single bond length(1.54 Å). Does this imply that the middle C¬C bond in butadieneis weaker or stronger than the average C¬C singlebond? (d) Based on your answer for part (c), discuss what additional aspects of bonding in butadiene might supportthe shorter middle C¬C bond.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter7: Covalent Bonding
Section: Chapter Questions
Problem 78QAP: A compound of chlorine and fluorine, CIFx, reacts at about 75C with uranium to produce uranium...
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Butadiene, C4H6, is a planar molecule that has the following
carbon–carbon bond lengths:(a) Predict the bond angles around each of the carbon atoms
and sketch the molecule. (b) From left to right, what
is the hybridization of each carbon atom in butadiene?
(c) The middle C¬C bond length in butadiene (1.48 Å) is
a little shorter than the average C¬C single bond length
(1.54 Å). Does this imply that the middle C¬C bond in butadiene
is weaker or stronger than the average C¬C single
bond? (d) Based on your answer for part (c), discuss what additional aspects of bonding in butadiene might support
the shorter middle C¬C bond.

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