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b. One mole of an ideal gas initially at 300.0 K and 25.0 L is isothermally compressed by a constant external pressure equal to the final pressure in 5a (above). At the end of the process, P = Pext: Because Pas did not equal Pext during the process, this process is irreversible. The initial volume is 25.0 L and the final volume is 10.0 L. The temperature of the surroundings is 300.0 K. Calculate q, w, AE and AH, ASSYS, ASSurr, AStotal, and AG.

b. One mole of an ideal gas initially at 300.0 K and 25.0 L is isothermally compressed by a constant external pressure equal to the final pressure in 5a (above). At the end of the process, P = Pext: Because Pas did not equal Pext during the process, this process is irreversible. The initial volume is 25.0 L and the final volume is 10.0 L. The temperature of the surroundings is 300.0 K. Calculate q, w, AE and AH, ASSYS, ASSurr, AStotal, and AG.

Physical Chemistry
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter2: The First Law Of Thermodynamics
Section: Chapter Questions
Problem 2.41E: A 2.50-mol sample of gas is compressed isothermally from 20.0 L to 5.00 L under a constant external...
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b. One mole of an ideal gas initially at 300.0 K and 25.0 L is isothermally compressed by a constant external pressure equal to the final pressure in 5a (above). At the end of the process, Pas = Pext. Because Pas did not equal Pext during the process, this process is irreversible. The initial volume is 25.0 L and the final volume is 10.0 L. The temperature of the surroundings is 300.0 K. Calculate q, w, AE and AH, ASSYS, AS surr, AStotal, and AG.
Transcribed Image Text:b. One mole of an ideal gas initially at 300.0 K and 25.0 L is isothermally compressed by a constant external pressure equal to the final pressure in 5a (above). At the end of the process, Pas = Pext. Because Pas did not equal Pext during the process, this process is irreversible. The initial volume is 25.0 L and the final volume is 10.0 L. The temperature of the surroundings is 300.0 K. Calculate q, w, AE and AH, ASSYS, AS surr, AStotal, and AG.
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