At 25˚C, the rhombic form of sulfur is the most stable form, which undergoes a transition at 95˚C to the monoclinic form. The molar enthalpy of the transition from the rhombic to the monoclinic sulfur is 0.402 kJmol-1 at 95˚C. n = 3.0 mol Ar V = 1 L T = 358K n = 1.0 mol Ne V = 1 L T = 298 K n = 3.0 mol Ar + 1.0 mol Ne V = 2 L The molar entropy of the rhombic form of sulfur at 25˚C is 31.88 J K-1 mol-1 . What is the molar entropy of the monoclinic form of sulfur at 25˚C?
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
At 25˚C, the rhombic form of sulfur is the most stable form, which undergoes a transition at 95˚C to the monoclinic form. The molar enthalpy of the transition from the rhombic to the monoclinic sulfur is 0.402 kJmol-1 at 95˚C. n = 3.0 mol Ar V = 1 L T = 358K n = 1.0 mol Ne V = 1 L T = 298 K n = 3.0 mol Ar + 1.0 mol Ne V = 2 L The molar entropy of the rhombic form of sulfur at 25˚C is 31.88 J K-1 mol-1 . What is the molar entropy of the monoclinic form of sulfur at 25˚C?
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