Approximately 6 mL of concentrated perchloric acid (72%) was transferred to a bottle and diluted with about 1.0L of water. A sample containing 250.0 mg of primary standard sodium tetraborate (Na2B407 .10H2O, FW= 381.42 g/mol) was dissolved in 50.00 mL water and required 27.25 mL of the HCIO4 solution to reach the methyl red end point. A 25.00 mL solution of an unknown NH3 sample required 13.24 mL of the HCIO4 solution. Calculate the molarity of the NH3.
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- 3 .... 1V * 00 < (O SI Sona Psychology Research Pa X Question 5 of 9 In a titration of 49.0 mL of a 0.500 M solution of a diprotic acid H2C3H2O4 (malonic acid) with 0.255 M NaOH, how many grams of NaOH are required to reach the second equivalence point? (MW_NAOH = 39.997 g/mol) %3D 6 2 4. 9. 8. /- acBook Air psa DD F7 F3 F4 F5 F8 F10 69. F12 23 24 2 3. 4. 9. 8. 6 delete A %31 H M B. 10. command command optionConsider the reaction of a 20.0 mL of 0.220 M CsH5NHCI (Ka = 5.9 x 10-6) with 12.0 mL of 0.215 M CSOH. a) Write the net ionic equation for the reaction that takes place. Be sure to include the proper phases for all species within the reaction. b) What quantity in moles of CsHsNH+ would be present at the start of the titration? c) What quantity in moles of OH- would be present if 12.0 mL of OH- were added? d) What species would be left in the beaker after the reaction goes to completion?1) What is the reason 2) In order to determine the hardness of water, 100 mL sample is taken. After neutralizing the sample, pH 10 buffer solutions and Erichrom black-T indicator are added. This sample is titrated with 10.7 mL of the solution containing 3.7225 g EDTA in 1 L distilled water. Calculate the hardness of water in terms of considering the amount of CaCO3 present in the sample. (Mwt Ca:40 g/mole, O:16 g/mole, C:12 g/mole, EDTA: 372,25 g/mole)
- If a 0.3 M solution of NaOH was used to titrate 100 mL of 0.3 M solution of CH3COOH (Ka =1.8 x 10 -5) and the following volumes of NaOH were recorded: 102, 97, 99, 98, 101, 106 mL. The pH Value is………………when added 99.0 mL of 0.3 M NaOH The pH of the solution at the equivalence point more than 7 Because................................... Calculate the 99% confidence limits of the mean? And use them to decide whether there is any evidence of systematic error? [ hints: For N=6 and the 99 % confidence interval, the value of t is 4.03].3. A solution was prepared by adding 4.95 g sodium acetate (NaC;H;O2) to 250.0 mL of 0.150 M acetic acid (K = 1.75 x 10). Assume negligible volume change. a) What is the pH of the resulting solution? PH: pk2 + log CH3 02) moles saium 4.959 0.06 mol %3D 2cent %3D 82gmu H: -log (1.73x 10) + log 0.24 moles 2cete 250 x 0.15 IL :00375 1000me PH : 4 1.96 O.06 (N2 G Hs0): 0.24m 0.230 L O.0375 : CCHS COOH): 0 15 m Assume 125.0 mL of the solution prepared above was put into a beaker and 82 mg of NaOH was added to it. What is the pH of this new mixture? b)5. A 300.0 mg sample containing Na,CO3, NaHCO3 and NaOH and inert material either alone or in some combination was dissolved and titrated with 0.1000 M HCI the titration required 24.41 mL to reach the phenolphthalein endpoint. And an additional 8.67 mL to reach the methyl red endpoint. Determine the composition of the sample and calculate the percent of each titrated component.
- Be sure to answer all parts. Find the pH during the titration of 20.00 mL of 0.1000 M triethylamine, (CH3CH2)3N (K, = 5.2 x 10), with 0.1000 M HCl solution after the following additions of titrant. %3D (a) 10.00 mL: pH =9.72 (b) 20.70 mL: pH =|8.25 (c) 28.00 mL: pH =|10.17 %3DAn unknown sample containing mixed alkal (NaOH NaHCO or Na,CO) was analyzed using the double flask method, A 250 mg sample was dissolved in 250 m CO3 free water. A 20.0 mL aliquot of this sample required 11.3 ml. of 0.009125 M HCl solution to reach the phenolphthalein end point. Another 29.0 ml aliquot of the sample was bitrated to the bromocresol green endpoint using 31.1 ml of the standard acid. How many millimoles of the components are there in the original solid sample) 0-928 mmol No. 0.0103 mmol NaOH 0078 m N.CO Cannot be determined 012 mol NaC0, 197 minol NaHCO 129 mmol NaOH, 097ml NajcoA 2.1562 g sample that may contain NaOH, NaHCO3 and Na2CO3 alone or in compatible mixtures reqıires 31.2 ml of 0.1082 M HCl for titration to the phenolphthalein end point and additional 52.4 ml of the same acid to bromocresol green end point. Calculate the percentages of compound(s) in the sample (M. Mass of NaOH:40 g/mol, M. Mass of NaHCO3: 84.01 g/mol, M. Mass of Na2CO3: 105.99 g/mol)?
- A 0.5843-g sample of a plant food preparation was analyzed for its N content by the Kjeldahl method, the liberated NH3 being collected in 50.00 mL of 0.1062 M HCl. The excess acid required an 11.89 mL back-titration with 0.0925 M NaOH. Express the results of this analysis in terms of (a) %N (b) %urea, H2NCONH2 (c) %(NH4)2SO4 (d) %(NH4)3PO4Suppose that you want to titrate a sample of vinegar with standard sodium hydroxide solution to determine the concentration of acetic acid in it, and you want to use an indicator to help you determine the end-point. Which of the following indicator would be suitable? (A) Bromocresol Green (Ka ~ 2.0 x 10–5; color: yellow in acid; blue in base) (B) Methyl Red (Ka ~ 5.0 x 10–6; color: red in acid; yellow in base) (C) Bromothymol Blue (Ka ~ 6.0 x 10–8; color: yellow in acid; blue in base) (D) Any of themA sample containing the amino acid alanine, CH3CH(NH2)COOH, plus inert matter is analyzed by Kjeldahl method. A 2.00 g sample is digested, the ammonia is distilled and collected in 50.0 ml of 0.150 M H2SO4, and a volume of 9.0 ml of 0.100 M NaOH is required for back titration. Calculate the percent alanine in the sample.