(a) Please derive the Clapeyron equation and the Clausius-Clapeyron equation. clearly state all assumptions. (b) Diamond is metastable at atmospheric pressures and normal temperature. If the molar volume of diamond is smaller than that of the graphite, please draw the Gibbs free energy curves for diamond and graphite as a function of pressure at a constant temperature.

(a) Please derive the Clapeyron equation and the Clausius-Clapeyron equation. clearly state all assumptions. (b) Diamond is metastable at atmospheric pressures and normal temperature. If the molar volume of diamond is smaller than that of the graphite, please draw the Gibbs free energy curves for diamond and graphite as a function of pressure at a constant temperature.

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter16: Spontaneity Of Reaction

Section: Chapter Questions

Problem 32QAP

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