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- How will you synthesize cyclohexanecarboxaldehyde (cyclohexylmethanal) from the following reagents? (There are no restrictions on the reagents or the number of steps). (a) Cyclohexanone (b) Ethynylcyclohexane (c) Methyl cyclohexylformate (Remember: Formic acid is the IUPAC recognized name for Methanoic acid) (d) Cyclohexanecarboxylic acid (Cyclohexylmethanoic acid) (e) VinylcyclohexaneProvide reaction mechanisms for the following transformations2) reaction sequences to carry out those transformations. Draw the expected product of each step proposed. Substantial partial credit can be obtained for incomplete or incorrect answers. You may present your solutions on the following blank page if you need the the following reaction transformations, and propose room. H3C CH, H3C CH3 of HN- -NH HO,C Co,H но H,C CH3 CEN OCH3 OCH3
- All rearrangements we have discussed so far have involved generation of an electron-deficient carbon followed by a 1,2-shift of an atom or a group of atoms from an adjacent atom to the electron-deficient carbon. Rearrangements by a 1,2-shift can also occur following the generation of an electron-deficient oxygen. Propose a mechanism for the acid-catalyzed rearrangement of cumene hydroperoxide to phenol and acetone.Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.Using your reaction roadmaps as a guide, show how to convert cyclohexane into adipoyl dichloride. Show all reagents and all molecules synthesized along the way.
- Using your reaction roadmap as a guide, show how to convert cyclohexane into hexanedial. Show all reagents and all molecules synthesized along the way.i) ii) 1. Propose a mechanism for the following reactions. H (CH3)2NH H* NaOH EtOHProvide reagents for the following transformations. You may use anything you like b) d) ? OCH3 ? ол ? ? Ph OH что ОН HO COOH
- What is the missing reagent needed to perform the following transformation? Assume mildly acidic catalysis. a) CH3NH2 b) CH2=NH c) (CH3)2NH d) CH3CH2NH2O Consider the following reaction scheme: (i) Suggest the reagent(s) that are suitable for this transformation. (ii) Draw a curved arrow mechanism for the transformation using the reagents i above. Reagent(s) O Consider the following reaction scheme. Identify compound E. H- Sing H Br Ph Bu3SnH, AIBN Toluene, 80 °C EProvide detailed step-wise mechanism for the following reaction. Be sure to show all intermediates, formal charges, and show the movement of electrons with curved arrows. a 4+H₂Q 044 OH