A dilute peroxide solution was prepared by quantitatively diluting 10 mL stock H2O2 (MW = 34.0147) to 250mL using a volumetric flask. 50 mL aliquot of the diluted peroxide solution was titrated using the previously standardized KMnO4 in problem 1. Titration of the sample required 29.00 mL titrant and the blank containing 50 mL 1:5 H2SO4 required 0.75 mL of the standard KMnO4. Calculate the concentration in %w/v of the stock H2O2. (Hint: H2O2 produces O2 under acidic condition). Follow sig. Fig

A dilute peroxide solution was prepared by quantitatively diluting 10 mL stock H2O2 (MW = 34.0147) to 250mL using a volumetric flask. 50 mL aliquot of the diluted peroxide solution was titrated using the previously standardized KMnO4 in problem 1. Titration of the sample required 29.00 mL titrant and the blank containing 50 mL 1:5 H2SO4 required 0.75 mL of the standard KMnO4. Calculate the concentration in %w/v of the stock H2O2. (Hint: H2O2 produces O2 under acidic condition). Follow sig. Fig

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter16: Applications Of Neutralization Titrations

Section: Chapter Questions

Problem 16.20QAP

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Approximately 6 mL of conc. perchloric acid ( 72% ) was transferred to a bottle and diluted with about 1 liter of water. A sample containing 251.5 mg of primary standard Na2B4O7.10H2O (Fwt= 382g/mol) required 27.41 mL of the HClO4 solution to reach the methyl red end point. What is the molar concentration of the HClO4 solution? Na2B4O7.10H2O + HClO4 ------------> NaClO4 H2B4O7.10H2O
A 22.41 mL of NaOH solution is required to reach the phenolphthalein endpoint in the standardization with 0.276 g of solid, monoprotic primary standard acid (MW 128.33) in a 25.00 mL solution. 12.34 mLof the same NaOH solution was added to titrate 5 mL of vinegar solution to the endpoint. Calculate the mass of acetic acid in this vinegar solution (d = 1.005 g/mL).
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A Na2CO3 standard solution is prepared by transferring 2.4817 grams of primary standard-grade sodium carbonate to a 250.0- mL volumetric flask, dissolving the sample in ~100 mL of distilled deionized water, and diluted to the mark. A 25.00-mL aliquot is taken and titrated with 42.65 mL of HCl solution to the bromocresol green endpoint. Calculate the concentration of the HCI solution. a. 0.1098 M b. 0.3196 M c. 0.05490 M d. 0.1598 M
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Approximately 6.0mL of concentrated perchloric acid (70%) was transferred to a bottle and diluted with about 1.0L of water. A sample containing 251.5 mg of primary standard Na2B4O7.10H2O required 27.41 mL of the HClO4 solution to reach the methyl red end point. Calculate the molar concentration of the HClO4 (Fwt = 382g/mole)
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