7. Sodium nitrite was assayed by residual titration with 0.1N potassium permanganate and 0.1 N oxalic acid. What is the gram-equivalent weight (gew) of sodium nitrite? (NaNO₂= 68.99g/mol) NaNO₂+ KMnO4+H₂SO4Ⓡ HNO3 + MnSO4 + Na₂SO4 + K₂SO4 + H₂O KMnO4 + H₂C₂O4 + H₂SO4Ⓡ MnSO4 + K₂SO4 + CO₂ + H₂O
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- A 0.1064-g of aldrin pesticide sample was decomposed and the liberated chloride was extracted using water. It was titrated with 23.28 mL of 0.03337 M AgNO 3 using a chromate indicator. Express results in % aldrin (C 12H 8Cl 6, MM=365). 63.21 % 22.12 % 17.28 % 44.42 %7. Sodium nitrite was assayed by residual titration with 0.1N potassium permanganate and 0.1 N oxalic acid. What is the gram-equivalent weight (gew) of sodium nitrite? (NaNO2=68.99g/mol) NaNO2+ KMnO4 +H2SO4 ® HNO3 + MnSO4 + Na2SO4 + K2SO4 + H2O KMnO4 + H2C2O4 + H2SO4 ® MnSO4 + K2SO4 + CO2 + H2O ㅋDirect titration: 10.90 ± 0.02 mL of an unknown KHP solution required 11.72 ± 0.02 mL of 0.1090 ± 0.0006 M NaOH to reach the end point. What is the concentration of KHP in the unknown solution reported with absolute uncertainty? If the unknown solution was prepared by dissolving 5.128 g of the unknown KHP (204.22 g/mol) in 100.00 mL of water, what is the weight percent of KHP in the sample?
- 5. A 300.0 mg sample containing Na,CO3, NaHCO, and NaOH and inert material either alone or in some combination was dissolved and titrated with 0.1000 M HCI the titration required 24.41 ml to reach the phenolphthalein endpoint. And an additional 8.67 mL to reach the methyl red endpoint. Determine the composition of the sample and calculate the percent of each titrated component.5. A 300.0 mg sample containing Na,CO3, NaHCO3 and NaOH and inert material either alone or in some combination was dissolved and titrated with 0.1000 M HCI the titration required 24.41 mL to reach the phenolphthalein endpoint. And an additional 8.67 mL to reach the methyl red endpoint. Determine the composition of the sample and calculate the percent of each titrated component.Exp. 4 Volhard method In an experiment of determination of KBr (g%) by volhard method In a flask; 15ml KBr was taken 25 ml 0.05M AgNO3 1 ml nitric acid 1 ml ferric alum indicator Then titration with 0.05M KSCN was done The end point was =15 ml Calculate the mass of KBr in g%
- Titration of a 0.492-g KH₂PO4 used 25.6 mL of 0.112M NaOH. What is the percent purity of KH₂PO4? MW KH₂PO4 = 136.1 g/mol H₂PO4¹ + OH¹ HPO4² + H₂OA 0.9092g sample of wheat flour was analyzed by Kjeldahl method. The ammonia formed was distilled into 50.00 mL of 0.05063 M HCl; a 7.46 mL back titration with 0.04917 M NaOH was required. Calculate the % protein in the flour. Input the value only. Express in 2 SF.Titration of 50.00 mL of 0.04715 M Na2C2O4 required 39.25 mL of a potassium permanganate solution.MnO4- + 5H2C2O4 + 6H+ → 2Mn2+ + 10CO2(g) + 8H2OCalculate the molar concentration of the KMnO4 solution.
- An unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double flask method. A 250 mg sample was dissolved in 250 mL CO, free water. A 20.0 mL aliquot of this sample required 11.3 mL of 0.009125 M HCI solution to reach the phenolphthalein end point. Another 29.0 mL aliquot of the sample was titrated to the bromocresol green endpoint using 31.1 mL of the standard acid. What is/are the component/s of the sample? O NazCO3 only NaHCO3 only O NAHCO3 and Na>CO3 NaOH and NazCO3 O Cannot be determinedA 0.5264-g sample containing KBr is dissolved in 50 mL distilled water. Titrating with 0.04738 M AgNO3 requires 24.57 mL to reach the Mohr endpoint. A blank titration requires 0.75 mL to reach the same endpoint. Report the % (w/w) KBr (MM = 119.0) in the sample. 51.02 % 26.19% 12.76 % 25.51 %An unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double flask method. A 250 mg sample was dissolved in 250 mL CO, free water. A 20.0 mL aliquot of this sample required 11.3 mL of 0.009125 M HCI solution to reach the phenolphthalein end point. Another 29.0 mL aliquot of the sample was titrated to the bromocresol green endpoint using 311 mL of the standard acid. What is/are the component/s of the sample? O Cannot be determined O NAHCO3 only O NAOH and Na,CO3 O NazCO3 only O NAHCO, and Na2CO3