6. To observe the effect of temperature on reaction rate, the reaction between MnO4 aq) and C204(ag) in acidic media is performed according to the given redox reaction: 2 MnO4 (aq) + 16 H*(aq) + 5 C204²(aq) → 10 CO2(g) + 2 Mn²*(aq) + 8 H2O(1) At various temperatures, the rate constants were determined experimentally as follows: k (M s') 5.03x10$ 3.68×104 T (°C) 20 35 60 6.71x103 90 0.119 (a) Determine Ea for this reaction by a graphical method (see the graph given below). (b)Determine Ea using Arrhenius equation using tabulated data. (c) Calculate the value of the rate constant, k at 100°C. -2 .......

Chemistry for Engineering Students
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Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
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6. To observe the effect of temperature on reaction rate, the reaction between MnO, ag) and
C204(ag) in acidic media is performed according to the given redox reaction:
2 MnO4 (aq) + 16 H*(aq) + 5 C204²(aq) → 10 CO2(g) + 2 Mn²"(aq) + 8 H2O(1)
At various temperatures, the rate constants were determined experimentally as follows:
k (M s')
5.03x105
T (°C)
20
35
3.68×104
60
6.71×103
90
0.119
(a) Determine Ea for this reaction by a graphical method (see the graph given below).
(b) Determine E. using Arrhenius equation using tabulated data.
(c) Calculate the value of the rate constant, k at 100°C.
-2
-4
兰 -6
-8
-10
-12
0.0025
0.0027
0.0029
0.0031
0.0033
0,0035
1/T (K)
Transcribed Image Text:6. To observe the effect of temperature on reaction rate, the reaction between MnO, ag) and C204(ag) in acidic media is performed according to the given redox reaction: 2 MnO4 (aq) + 16 H*(aq) + 5 C204²(aq) → 10 CO2(g) + 2 Mn²"(aq) + 8 H2O(1) At various temperatures, the rate constants were determined experimentally as follows: k (M s') 5.03x105 T (°C) 20 35 3.68×104 60 6.71×103 90 0.119 (a) Determine Ea for this reaction by a graphical method (see the graph given below). (b) Determine E. using Arrhenius equation using tabulated data. (c) Calculate the value of the rate constant, k at 100°C. -2 -4 兰 -6 -8 -10 -12 0.0025 0.0027 0.0029 0.0031 0.0033 0,0035 1/T (K)
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ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning