6. Explain why the aromatic protons in the molecules below resonate at the approximate frequencies shown in a ¹H nmr spectrum (general region AND relative values to each other). Ensure that you address the reason for the difference in resonance frequencies between each position (o,m,p) and include any relevant structures in your answer. Note this does not require you to calculate the expected shifts. 6.73 ppm 6.79 ppm 7.24 ppm

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Chapter1: Chemical Foundations
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6. Explain why the aromatic protons in the molecules below resonate at the approximate
frequencies shown in a ¹H nmr spectrum (general region AND relative values to each
other). Ensure that you address the reason for the difference in resonance frequencies
between each position (o,m,p) and include any relevant structures in your answer. Note
this does not require you to calculate the expected shifts.
H
-Ph
6.73 ppm
7. Dimerisation of terminal alkenes has been shown to be achievable using Ruthenium catalysts
however a mixture of products results as shown in the example below.
C-Me--Ru(PPh3)H3 (catalyst)
80 °C, C6D6
H
6.79 ppm
Ph
7.24 ppm
H
+
Ph
Ph
H
B
H
Ph
H
H
Ph
Explain how ¹H NMR could be used to distinguish between the three possible products A, B
and C (other than by using tables to predict chemical shifts). In your answer give detail
including approximations of any numerical values that would be used and an explanation of the
reasons why the values differ for the 3 molecules.
Ph
Transcribed Image Text:6. Explain why the aromatic protons in the molecules below resonate at the approximate frequencies shown in a ¹H nmr spectrum (general region AND relative values to each other). Ensure that you address the reason for the difference in resonance frequencies between each position (o,m,p) and include any relevant structures in your answer. Note this does not require you to calculate the expected shifts. H -Ph 6.73 ppm 7. Dimerisation of terminal alkenes has been shown to be achievable using Ruthenium catalysts however a mixture of products results as shown in the example below. C-Me--Ru(PPh3)H3 (catalyst) 80 °C, C6D6 H 6.79 ppm Ph 7.24 ppm H + Ph Ph H B H Ph H H Ph Explain how ¹H NMR could be used to distinguish between the three possible products A, B and C (other than by using tables to predict chemical shifts). In your answer give detail including approximations of any numerical values that would be used and an explanation of the reasons why the values differ for the 3 molecules. Ph
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