6) The substitution reaction below to produce 1-iodobutane was performed using 1-bromobutane at a 0.1 M concentration and sodium iodide at a 0.1 M concentration. What would the rate law be for the reaction below? How would you expect the rate of the reaction to change if a 0.2 M concentration of sodium iodide was used? How would you expect the rate constant to change? Explain. Nal (0.1 M) Br acetone (0.1 M)

6) The substitution reaction below to produce 1-iodobutane was performed using 1-bromobutane at a 0.1 M concentration and sodium iodide at a 0.1 M concentration. What would the rate law be for the reaction below? How would you expect the rate of the reaction to change if a 0.2 M concentration of sodium iodide was used? How would you expect the rate constant to change? Explain. Nal (0.1 M) Br acetone (0.1 M)

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions

Section: Chapter Questions

Problem 20.27P

See similar textbooks

Similar questions

Below is the equation for a nucleophilic substitution reaction and some experimental data. CH3CH2Br + CH3COO- ⇌ CH3CH2CO2CH3 + Br- ΔH=-75 kJ/mol Rate = k [CH3CH2Br][CH3COO-] Which reaction energy profile would be the best representative of the data provided?
The following is a nucleophilic substitution reaction of S-3-chloro-2-methylhexane with "CN. The experimental rate law for this reaction is Rate k [S-3-chloro-2-methylhexane] CH3 H;C. C. C H. CH3 CEN H2 H. The mechanism for this reaction is SN1 Draw the orgamic molecule(s) which is(are) formed in this reaction. Do not include molecules like H,O or HCl. Draw the specific configuration (R or S) at any chiral carbons within your product(s). If both configurations are formed in the product(s), draw both as separate molecules/products.
Which of the following represents the transition state of the rate- determining step in the reaction between 2-bromopropane and sodium methoxide leading to elimination? H;C H;C CH, S0----H----CH2 CH3 -Br -Br 2 H3C CH, Br H3C CH: ---Br 3 H3C а. 1 b. 2 с. 3 d. 4
The clecona position of nitramide. ) Solutionat 25°C in.ayueous. NH2NO2 la)- has the Follacing reahonship between rate and concentrahionwhere the bracket anund thse formula indicates concentration and K is a Constant caled the rate constant. hate K [NH2NO2] IF the value of Kis l6.49x10s-1 rate of the reaction when MH,NO=0.3016M? -5 what is the Ms-
Below is the equation for a nucleophilic substitution reaction and some experimental data. CH3CH2Br + CH3COO- ⇌ CH3CH2CO2CH3 + Br- Rate = k [CH3CH2Br][CH3COO-] Which mechanism would best fit the data?
How many transition states and intermediates would the reaction profile have for the reaction shown below?
CF2Cl2 can be prepared from the nucleophilic substitution of another alkyl halide CCl4 in the presence of excess HF. CCl4 + 2HF -----> CF₂Cl2 + 2HCI. rate = k[CCl4] How long will it take for this reaction to reach 90% completion if the the rate constant for the reaction is 1.5 x 10- 4 5-1? Give your answer in hours to 1 d.p. Time required: hours
2- Write step-by-step mechanism for the following reaction: Cul R1 но .*...... ....... ........
The following figure shows the energy profile of a nucleophilic substitution reaction. Potential energy :ÖH H HII.C H C-1 H HO--C---I HH Reaction coordinate H -CH HO–CHITH H + 1 According to this, it is correct to affirm: O The activation energy (4G°) shows that it is thermodynamically favorable. O Represents a reaction that occurs in one step where a pentavalent chemical species is formed. O The intermediate has lower energy than any transition state. O The formation of the intermediate releases energy and is therefore thermodynamically favourable.
19. Predict the relative rates of these reactions. That is, select 1 next to the reaction with the fastest rate, 2 next to the reaction with the next fastest rate, and so onNote for advanced students: you may assume these reactions all take place in a polar aprotic solvent, like DMSO.
The following initial rate data are for the reaction of tertiary butyl bromide with hydroxide ion at 55 oC:(CH3)3CBr + OH- (CH3)3COH + Br- Experiment [(CH3)3CBr]o, M [OH-]o, M Initial Rate, Ms-1 1 0.378 0.324 4.23×10-3 2 0.378 0.648 4.23×10-3 3 0.756 0.324 8.47×10-3 4 0.756 0.648 8.47×10-3 Complete the rate law for this reaction in the box below.Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant is _______s-1.
The propene reaction with OH radical has a reaction rate constant 2.63 * 10-11 cm3/(molecules*s) and the reaction rate constant with O3 is 1.13*10-17 cm3/(molecules*s). Under polluted conditions (OH=1*106 molecules/cm3 and O3=125 ppb), which reaction dominates? (Assume T=30°C)