5) The volume of several aqueous copper sulfate (CuSO4) solutions was precisely measured at SATP. All of the solutions were made by adding copper sulfate to 100.00 g of water. ncopper sulfate (mol) Vsolution (mL) 0 100.18 0.0330 100.16 0.0696 100.36 0.111 100.81 0.156 101.62 First, estimate the concentration-dependent partial molar volume of copper sulfate in water by taking finite differences. Second, fit the data to a hyperbola and take a derivative of the hyperbola to accurately calculate the partial molar volume of copper sulfate in water at each concentration. Interpret the partial molar volume at infinite dilution - what must copper sulfate be doing to the nearby water molecules?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter12: Solutions
Section: Chapter Questions
Problem 12.106QE: In the 1986 Lake Nyos disaster (see the chapter introduction), an estimated 90 billion kilograms of...
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5)
The volume of several aqueous copper sulfate (CuSO4) solutions was precisely measured
at SATP. All of the solutions were made by adding copper sulfate to 100.00 g of water.
ncopper sulfate (mol)
Vsolution (mL)
0
100.18
0.0330
100.16
0.0696
100.36
0.111
100.81
0.156
101.62
First, estimate the concentration-dependent partial molar volume of copper sulfate in
water by taking finite differences. Second, fit the data to a hyperbola and take a
derivative of the hyperbola to accurately calculate the partial molar volume of copper
sulfate in water at each concentration. Interpret the partial molar volume at infinite
dilution - what must copper sulfate be doing to the nearby water molecules?
Transcribed Image Text:5) The volume of several aqueous copper sulfate (CuSO4) solutions was precisely measured at SATP. All of the solutions were made by adding copper sulfate to 100.00 g of water. ncopper sulfate (mol) Vsolution (mL) 0 100.18 0.0330 100.16 0.0696 100.36 0.111 100.81 0.156 101.62 First, estimate the concentration-dependent partial molar volume of copper sulfate in water by taking finite differences. Second, fit the data to a hyperbola and take a derivative of the hyperbola to accurately calculate the partial molar volume of copper sulfate in water at each concentration. Interpret the partial molar volume at infinite dilution - what must copper sulfate be doing to the nearby water molecules?
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