5*) a) The reaction A B has been experimentally determined to be second order. The initial rate is 0.0100 M/s at an initial concentration of [A] of 0.100 M. What is the initial rate at [A]o = 0.500 M?

Chemistry: The Molecular Science
5th Edition
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Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 21QRT: The reaction of CO(g) + NO2(g) is second-order in NO2 and zeroth-order in CO at temperatures less...
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5*) a) The reaction A B has been experimentally determined to be second order. The initial
rate is 0.0100 M/s at an initial concentration of [A] of 0.100 M. What is the initial rate at
[A]o = 0.500 M?
b) The reaction below was experimentally determined to be first order with respect to O2
and second order with respect to NO.
O2(g) + 2 NO(g) → 2 NO2(g)
The diagrams provided represent reaction mixtures in which the number of each type of
molecule represents its relative initial concentration. Which mixture has the fastest
initial rate? Explain.
KEY:
= 02
= NO
(i)
(ii)
(iii)
Transcribed Image Text:5*) a) The reaction A B has been experimentally determined to be second order. The initial rate is 0.0100 M/s at an initial concentration of [A] of 0.100 M. What is the initial rate at [A]o = 0.500 M? b) The reaction below was experimentally determined to be first order with respect to O2 and second order with respect to NO. O2(g) + 2 NO(g) → 2 NO2(g) The diagrams provided represent reaction mixtures in which the number of each type of molecule represents its relative initial concentration. Which mixture has the fastest initial rate? Explain. KEY: = 02 = NO (i) (ii) (iii)
c) A certain decomposition reaction has a half-life that depends on the initial
concentration of the reactant, and its rate is observed to slow down as the reaction
proceeds. Identify which statement is most likely correct for this reaction and explain
why the other statements are incorrect.
(i) The half-life of the reaction increases as the initial concentration increases.
(ii) A doubling of the initial concentration of the reactant results in a quadrupling of the
rate.
(iii) A plot of the natural log of the concentration of the reactant as a function of time is
linear.
Transcribed Image Text:c) A certain decomposition reaction has a half-life that depends on the initial concentration of the reactant, and its rate is observed to slow down as the reaction proceeds. Identify which statement is most likely correct for this reaction and explain why the other statements are incorrect. (i) The half-life of the reaction increases as the initial concentration increases. (ii) A doubling of the initial concentration of the reactant results in a quadrupling of the rate. (iii) A plot of the natural log of the concentration of the reactant as a function of time is linear.
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