4.7 Aniline can be synthesized from benzene by using correct synthetic schemes. Choose one scheme that can be used to produce aniline from benzene from the given options A. B. C. NO₂ H₂SO4 D. HNO3 H₂SO4 1. SnCl, HyO* 2. HO HNO3 H₂SO4 Product Product Product Product 1. SnCl, HyO* 2. HO H₂/Pd Ethanol HNO₂ H₂SO4 1. NaOH, 300 °C 2. H₂O* Aniline Aniline Aniline Aniline

4.7 Aniline can be synthesized from benzene by using correct synthetic schemes. Choose one scheme that can be used to produce aniline from benzene from the given options A. B. C. NO₂ H₂SO4 D. HNO3 H₂SO4 1. SnCl, HyO* 2. HO HNO3 H₂SO4 Product Product Product Product 1. SnCl, HyO* 2. HO H₂/Pd Ethanol HNO₂ H₂SO4 1. NaOH, 300 °C 2. H₂O* Aniline Aniline Aniline Aniline

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter10: Alcohols

Section: Chapter Questions

Problem 10.52P: Alcohols are important for organic synthesis, especially in situations involving alkenes. The...

See similar textbooks

Similar questions

Which of the following provides a synthetic route to convert 3-iodo-2-methyl-1- butene into 2-methyl-2-butene? 1. NaOH; 2. H₂, Pt 1. H₂, Pt; 2. Br2 1. H₂, Pt; 2. NaOEt 1. H₂, Ni₂B; 2. KOtBu 1. H₂, Pt; 2. KOtBu
4. (5 pts) Extra credit Explain why the "benzyne" reaction (Hint: look at one of the major products) always yields a 50/50 mixture of isomers. A drawing or two would be great!
11. (24 pts) (a) Similar to alkanes, hydrogen gas can undergo radical bromination according to the reaction below. Propose a chain-reaction mechanism for this reaction, including an initiation step, propagation steps, and two plausible termination steps. The homolytic bond dissociation energy for Br-Br is 46 kcal mole-, for H-Br is 88 kcal mole and for H-H is 104 kcal mole. hv Н-Н + Вr-Br 2 Н-Br (b) Calculate the overall AH for the above propagation steps (show all work).
4. 3. Complete the equation with a structural formula of the organic product. HH HH C-C H H H С-С' `ОН CC /1/1 HH HH H*/ Cr₂O7²- Write a structure for the oxidation product if ethanol is allowed to react with excess acidic dichromate. CH3CH₂OH excess H*/ Cr2O7²-
Alcohols are important for organic synthesis, especially in situations involving alkenes. The alcohol might be the desired product, or the OH group might be transformed into another functional group via halogenation, oxidation, or perhaps conversion to a sulfonic ester derivative. Formation of an alcohol from an alkene is particularly powerful because conditions can be chosen to produce either the Markovnikov or non-Markovnikov product from an unsymmetrical alkene. Using your reaction roadmap as a guide, show how to convert 4-methyl-1-pentene into 5-methylhexanenitrile. You must use 4-methyl-1-pentene and sodium cyanide as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.
a. 0 b. 1 с. 2 d. 3 e. 4 14. D-glucose is shown below. Which of the choices below is its enantiomer L-glucose? CHO II H OH IV HO H D-glucose H OH HO- ČH2OH a.I H- Ja CHO CHO СНО CHO CHO H- HO- H OH H- -ОН но H- Но- - HO- -- Но H- HO- H OH HO- H- HO- H- HO- HO -H- Но- H- HO H- H OH ČH,OH HO H H- HO- HO H H OH CH,OH CH2OH CH2OH CH2OH a. b. С. d. e. 15. Which of the following statements describes lipids?
What is the organic product formed in the following reaction? NaOC₂H₂ H+(aq) стеносли + OC₂H HOC₂H | -CH₂CH = ||| Select one: A. II B. I C. IV D. III ° -CH₂CH₂ OC₂HS IV -CH OC₂H₂ CH3 OH CH3 O OC₂H₂ bc₂Hs
6.) Predict the product of the following chemical reactions and state where the product (waste) sk waste should be disposed: Example: OH 1. NaBH4, ethanol CH;CH,CH,CH CH;CH,CH,CH 2. H3O* H Butanal 1-Butanol Waste: G704 (Non-halogenated organic solvents) 1. NaBH4, ethanol a.) Cyclohexanecarbaldehyde 2. H3O* b.) Sodium Flouride + 3-iodo-3-methylpentane (hint: substitution or eliminatic 2/3 H3O* c.) Benzoic acid + Phenol РС d.) 3-pentanol H2CrO4 e.) Cyclohexylmethanol
MCQ 16: In SN2 mechanism 'S' stands for A. subordinate B. substitution C. sub-reaction D. systemic reaction
a) b) c) d) e) 1) BH3/THF 2) H₂O2 NaOH (aq) cold Cl₂, H₂O HBr CH3CH₂OOCH₂CH3 1. Hg(OAc)2, H₂O 2. NaBH4 o 1) 03 (-78 °C) 2) (CH3)S H₂ Lindlar catalyst
5. 45. A. 43. The expected major product of the following reaction is: HBr ? I A) H₂C H What is the major product of the following reaction? A. H CH₂ CH₂ IIIIII OH CH3 CH₂ What is the product of the following reaction? + Br II B. Br H₂ B. 1. 2. H₂C H Hg(OAc)₂, H₂O NaBH₂ OH Pt B. B) D) CH Arrange the following carbocations in order of their decreasing stability (most stable first). H₂ C. III Br both A and B C. 'Br D. no reaction will occur -CH3 OH I>III>II D. II>III>I
b. 2-Methylhexane viewed along with the C3-C4 bond. 14 10. Which of the following is a cis-isomer or a trans-isomer? H. H. Br a. b. CH H. C. Write the initiation, propagation, and termination step for monochlorination of cyclohexa d. What is the major product for the following reaction? Cl, hv (Reactadi) d. What is the anticipated percent yield of the major product? (producti