4. What is a reaction mechanism?

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
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/5 C12-3-09 Explain the concept of a reaction mechanism. Include: rate-determining step
4.
What is a reaction mechanism?
5. Why is a bimolecular step more reasonable than a termolecular step?
6.
Considerthe following mechanism:
Step 1: ClO (aq) + H2O) → HCIO(aq) + OH'(aq)
[Slow]
Step 2: l'(aq) + HCIO aq) → HIO(aq) + Cl a«
(aq)
[Fast]
Step 3: OH (ag) + HIO(aq) → H2O
+10 (aq)
[Fast]
a.
What is the overall equation?
b. Identify any intermediates
С.
What is the rate determining step? Why did you choose this step?
d. In which step is the catalyst placed? Why is it put in this step?
e. Predict and explain the effect the following changes would have on the rate of the
reaction.
7 lowe,t
i.
Increasing the concentration of Clo-
ii.
Increasing the concentration of I
for frst
Transcribed Image Text:/5 C12-3-09 Explain the concept of a reaction mechanism. Include: rate-determining step 4. What is a reaction mechanism? 5. Why is a bimolecular step more reasonable than a termolecular step? 6. Considerthe following mechanism: Step 1: ClO (aq) + H2O) → HCIO(aq) + OH'(aq) [Slow] Step 2: l'(aq) + HCIO aq) → HIO(aq) + Cl a« (aq) [Fast] Step 3: OH (ag) + HIO(aq) → H2O +10 (aq) [Fast] a. What is the overall equation? b. Identify any intermediates С. What is the rate determining step? Why did you choose this step? d. In which step is the catalyst placed? Why is it put in this step? e. Predict and explain the effect the following changes would have on the rate of the reaction. 7 lowe,t i. Increasing the concentration of Clo- ii. Increasing the concentration of I for frst
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