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- 2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. b. CN Br Br CH₂ Revised F FWhich compound is the major product of the reaction below? QH (1) LIAIH,/ether N. N. N. (2) H* (dil.)/H,O (A) (B) HO, (C) (D) O Compound B O Compound A Compound C Compound DChoose the most correct set of reagents for the following reactions. 1. ? a O b O C O 으으 OH 2. ? OMe a. 1. MsCl, pyridine; 2. NaOCH3, CH3OH b. 1. HCI, pyridine; 2. NaOCH3, CH3OH c. 1. PCI 3, SOCI2; 2. NaOCH3, CH3OH d. 1. TsCl, pyridine; 2. NaOCH3, CH3OH e. 1. CH3O-, pyridine; 2. H* f. 1. Pl3, pyridine; 2. -OCH3
- Which alkene cannot be converted into an alkyl bromide with HBr, ROOR, hv, A? III IV A. B. C. D. E. All react Which synthetic route is best to give the major product shown below. ? x XA OH A. 1. BH3; 2. H₂O2, NaOH; 3. HBr; 4. CH3CO₂H B. 1. Br₂, 2. NaCCH; H₂, Lindlar's; 3. O3; 4. H₂O C. 1. NBS, hv, A; 2. H₂, Pd; 3. NaO₂CCH3 D. 1. NBS, hv, A; 2. NaCCH; 3. H₂2, Pd; 4. O3; 5. H₂O E. 1. NBS, hv, A; 2. H₂, Pd; 3. NaCCH; 4. 03; 5. H₂O Which synthetic route is best for the transformation shown below? OH ? OH A. 1. H₂SO4/heat; 2. HgOAC2, H₂O; 3. NaBH4 B. 1. HBr; 2. NaOH, DMSO C. 1. TsCl, pyr; 2. NaOH, DMSO D. 1. TsCl, pyr; 2. KOtBu; 3. BH3-THF; 4. H₂O2, NaOH E. 1. H₂SO4/heat; 2. BH3-THF; 3. H₂O2, NaOH =BChoose the most correct set of reagents for the following reactions. 1.? OMe 2. ? a. 1. MsCI, pyridine; 2. NaOH, H2O2, H2O b. 1. HCI, pyridine NaOCH3, CH;OH c. 1. Pl3, pyridine; 2. NaOCH3, CH;OH d. 1. TSCI, pyridine; 2. NaOCH3, CH3OH e. 1. CH30", pyridine; 2. H* f. 1. PBr3, pyridine; 2. H*e. f. a. C. d. 1. Provide the major product or reagents, as requested. b. Ph Ph Ph OH -COOH OH OH Morfools yd mis susitad OH ? mol of abiotio lyosnad to (lozbyd stand or not indoo Br Mg CO₂ H3O+ CH3Li (excess) conc. KMnO4 A Na₂Cr₂O7 H₂SO4 H₂O CH₂N2
- Complete the following reactions by providing any missing components. Provide all products formed and label as major/ minor when necessary. a. b. c. majc whe 1. Complete the following reactions by providing any missing components. Provide all products formed and label as major/minor when necessary. a. b. HNO3 H₂SO excess K2Cr2O7 OH H2SO4 Цон H₂SO H Tollen's Reagent ortho product H₂ Pd-C CH3OH H2SO4Provide the reagents necessary to carry out the following conversion. Br O 1. KOH; 2. Na2Cr2O7. 3. NaOH O 1. Na2Cr207/H2SO4: 2. H₂O 1. NaOH; 2. H₂O O 1. NaOH; 2. Na2Cr2O7/H2SO4/H20 O 1. NaOH; 2. H₂SO4: 3. H₂O OH2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. b. d. Br Br NH₂ HO₂C -NH₂ NH₂ HN- + N(CH3)3
- Provide the reagents necessary to carry out the following conversion. O zor HO. A. B. C. D. E. НО. OH 1. LIAIH4 2. H₂O NaBH/CH3OH DIBAL-H BH 3 THF C and D2. Show the products of reaction between each organometallic reagent below with the given proton source. a. b. C. d. e. Li MgBr Li MgBr + + + H H-Br OH H HSProvide the missing compounds and reagents in the reaction scheme. Identify reagent 5. OH reagent 2 reagent 1 H2SO4 но Compound 1 (conc.) 1) BH3 2) H,O, H,SO, (conc.) NaOH, H2O reagent 3 CrO3, H* A Compound 4 NABH4 1) O3 2) Zn, H;O* reagent 5 reagent 4 H,SO4 Compound 3 Compound 2 1) CH;MgBr (conc.) 2) H;O+ Identify reagent 1. Identify reagent 2. Identify reagent 3. Identify reagent 4. 1) CH3MGB1 2) H;O* H,SO̟ (conc.) H,SO, (conc.) H,SO, (conc.) CrO3, H+ 1) ВН, NaBH4 1) O3 NaBH, 2) H2O2 2) Zn, H3O* 1) CH,MgBr 1) BH3 NaBH, 2) H3O+ NABH, 2) H,O2 1) CH;MgBr 1) O3 1) BH3 1) O3 2) Zn, H3O* 2) H;0* 2) Zn, H,O+ 2) H,O2 1) O3 CrO3, H+ CrO3, H+ H,SO4 (conc.) 2) Zn, H,O* 1) CH; MgBr 2) H,0* 1) ВН, CrO3, H* 2) H,O,